Reactivity of the Dinuclear Arylstibonic Acid [2,6-MeS2C6H3Sb(O)(OH)2]2 toward H2SO4 and NaOH

被引：10

作者：

Beckmann, Jens ^{[1
]}

Hesse, Malte ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 07期

关键词：

PHOSPHONIC ACID; 2,4,6-TRIISOPROPYLPHENYLPHOSPONIC ACID; POLY(PHENYLACETYLENE)S BEARING; HELICITY INDUCTION; LIGANDS; CLUSTERS; FRAMEWORK; TITANIUM; CATIONS; DESIGN;

D O I：

10.1021/om900030m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses are reported of the molecular arylantimony oxo compounds [(2,6-Mes(2),C6H3Sb)(2)(O)(OH)(4)SO4] (1) and [Na-2(2,6-Mes(2)C(6)H(3)Sb)(4)O-4(OH)(10)center dot 2H(2)O] (2), which were obtained by the reaction of the dinuclear stibonic acid [2,6-Mes(2)C(6)H(3)Sb(O)OH](2) with aqueous H2SO4 and NaOH, respectively. The molecular structures of 1 and 2 were established by X-ray crystallography.

引用

页码：2345 / 2348

页数：4

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