State-to-state rate constants and rotational relaxation time in nitrogen

被引：20

作者：

Sharafutdinov, RG ^{[1
]}

Belikov, AE ^{[1
]}

Strekalov, ML ^{[1
]}

Storozhev, AV ^{[1
]}

机构：

[1] NOVOSIBIRSK CHEM KINET & COMBUST INST,NOVOSIBIRSK 630090,RUSSIA

来源：

CHEMICAL PHYSICS | 1996年 / 207卷 / 01期

关键词：

D O I：

10.1016/0301-0104(96)00030-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A recently developed 'quasiclassical ECS-E' fitting law for rotational transition rates has been used for a detailed comparison of theoretical and experimental data on rotational energy relaxation in nitrogen. A wide range of data on line broadening coefficients, ultrasonic absorption, population kinetics of isolated rotational levels exposed to laser pumping and population kinetics in a free jet has been analysed in order to refine the effective intermolecular parameters of the model thus providing a temperature-dependent form of the fitting law from 35 up to 1500 K.

引用

页码：193 / 201

页数：9

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