The electrochemical performance of SnO2 quantum dots@zeolitic imidazolate frameworks-8 (ZIF-8) composite material for supercapacitors

被引:74
作者
Gao, Yilong [1 ]
Wu, Jianxiang [1 ]
Zhang, Wei [1 ]
Tan, Yueyue [1 ]
Zhao, Jiachang [1 ]
Tang, Bohejin [1 ]
机构
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
关键词
SnO2 quantum dots@ZIF-8; Supercapacitors; Porous materials; Energy storage and conversion; OXIDATION; OXIDE;
D O I
10.1016/j.matlet.2014.04.175
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
SnO2\ quantum dots@ZIF-8 is successfully synthesized via a simple in-situ epoxide precipitation route and investigated as an electrochemical pseudo-capacitor material in 6 M KOH electrolyte. Structural characterizations illustrate the dispersion of SnO2 quantum dots in the ZIF-8. The porous structure combined with SnO2 quantum dots maximizes the utilization of active material, resulting in a high specific capacitance. A maximum specific capacitance of the SnO2 quantum dots@ZIF-8 can reach up to 931 F g(-1) at a scan rate of 5 mV s(-1), which is far higher than SnO2 quantum dots (241 F g(-1)) and ZIF-8 (99 F g(-1)). Meanwhile, SnO2 quantum dots@ZIF-8 exhibits a good cycling stability over 500 cycles. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:208 / 211
页数:4
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