Direct Evidence of Forster Resonance Energy Transfer for the Enhanced Photocurrent Generation in Dye-Sensitized Solar Cell

被引：14

作者：

Choi, Hyunbong ^{[1
,2
]}

Cho, Nara ^{[3
]}

Paek, Sanghyun ^{[3
]}

Ko, Jaejung ^{[3
]}

机构：

[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[3] Korea Univ, Dept Chem Mat, Sejong City 339700, South Korea

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2014年 / 118卷 / 30期

关键词：

NANOCRYSTALLINE TIO2 FILMS; CHARGE-TRANSFER; LIGHT; EFFICIENCY; COMPLEXES; VOLTAGE; SYSTEMS;

D O I：

10.1021/jp407475b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We meticulously designed organic antenna for the ruthenium phthalocyanine. A significant enhance-ment of photocurrent in JK-107 is attributed to a Forster energy transfer and intramolecular electron transfer from the antenna to the acceptor RuPc3. We demonstrate the direct evidence of Forster energy transfer and electron transfer for the enhanced photocurrent generation using photoluminescence spectroscopy and transient absorption spectroscopy, respectively.

引用

页码：16319 / 16327

页数：9

共 21 条

[1] DESIGN OF ANTENNA-SENSITIZER POLYNUCLEAR COMPLEXES - SENSITIZATION OF TITANIUM-DIOXIDE WITH [RU(BPY)2(CN)2]2RU(BPY(COO)2)22- [J].

AMADELLI, R ;

ARGAZZI, R ;

BIGNOZZI, CA ;

SCANDOLA, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7099-7103

[2] Swivel-cruciform oligothiophene dimers [J].

Bilge, Askin ;

Zen, Achmad ;

Forster, Michael ;

Li, Hongbo ;

Galbrecht, Frank ;

Nehls, Benjamin S. ;

Farrell, Tony ;

Neher, Dieter ;

Scherf, Ullrich .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (31) :3177-3182

[3] Stepwise Cosensitization of Nanocrystalline TiO2 Films Utilizing Al2O3 Layers in Dye-Sensitized Solar Cells [J].

Choi, Hyunbong ;

Kim, Sanghoon ;

Kang, Sang Ook ;

Ko, Jaejung ;

Kang, Moon-Sung ;

Clifford, John N. ;

Forneli, Amparo ;

Palomares, Emilio ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (43) :8259-8263

[4] Novel organic dyes containing bis-dimethylfluorenyl amino benzo[b]thiophene for highly efficient dye-sensitized solar cell [J].

Choi, Hyunbong ;

Lee, Jae Kwan ;

Song, Kihyung ;

Kang, Sang Ook ;

Ko, Jaejung .

TETRAHEDRON, 2007, 63 (15) :3115-3121

[5] Multistep electron transfer processes on dye co-sensitized nanocrystalline TiO2 films [J].

Clifford, JN ;

Palomares, E ;

Nazeeruddin, K ;

Thampi, R ;

Grätzel, M ;

Durrant, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (18) :5670-5671

[6] Increased light harvesting in dye-sensitized solar cells with energy relay dyes [J].

Hardin, Brian E. ;

Hoke, Eric T. ;

Armstrong, Paul B. ;

Yum, Jun-Ho ;

Comte, Pascal ;

Torres, Tomas ;

Frechet, Jean M. J. ;

Nazeeruddin, Md Khaja ;

Graetzel, Michael ;

McGehee, Michael D. .

NATURE PHOTONICS, 2009, 3 (07) :406-411

[7] Ru(II)-phthalocyanine sensitized solar cells: the influence of co-adsorbents upon interfacial electron transfer kinetics [J].

Morandeira, Ana ;

Lopez-Duarte, Ismael ;

O'Regan, Brian ;

Victoria Martinez-Diaz, M. ;

Forneli, Amparo ;

Palomares, Emilio ;

Torres, Tomas ;

Durrant, James R. .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (28) :5016-5026

[8] Stepped light-induced transient measurements of photocurrent and voltage in dye-sensitized solar cells: Application for highly viscous electrolyte systems [J].

Nakade, S ;

Kanzaki, T ;

Wada, Y ;

Yanagida, S .

LANGMUIR, 2005, 21 (23) :10803-10807

[9] CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES [J].

NAZEERUDDIN, MK ;

KAY, A ;

RODICIO, I ;

HUMPHRYBAKER, R ;

MULLER, E ;

LISKA, P ;

VLACHOPOULOS, N ;

GRATZEL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6382-6390

[10] Catalysis of recombination and its limitation on open circuit voltage for dye sensitized photovoltaic cells using phthalocyanine dyes [J].

O'Regan, Brian C. ;

Lopez-Duarte, Ismael ;

Victoria Martinez-Diaz, M. ;

Forneli, Amparo ;

Albero, Josep ;

Morandeira, Ana ;

Palomares, Emilio ;

Torres, Tomas ;

Durrant, James R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (10) :2906-2907

← 1 2 3 →