Molecular recognition by indoleacetic acid-imprinted polymers - effects of 2-hydroxyethyl methacrylate content

被引:11
|
作者
Kugimiya, A [1 ]
Takeuchi, T [1 ]
机构
[1] Hiroshima City Univ, Fac Informat Sci, Lab Synthet Biochem, Asaminami Ku, Hiroshima 7313194, Japan
关键词
molecular imprinting; molecular recognition; HEMA; indoleacetic acid;
D O I
10.1007/s00216-001-1176-8
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Molecularly imprinted polymers for indoleacetic acid were prepared by co-polymerizing N,N-dimethylaminoethyl methacrylate, 2-hydroxyethyl methacrylate (HEMA), and ethylene glycol dimethacrytate. The dependence of the affinity and selectivity of the imprinted polymers on HEMA content was evaluated chromatographically. The affinity was improved by increasing the HEMA content; the selectivity of the imprinted polymer was best when the HEMA content was approximately 30%, irrespective of monomer content.
引用
收藏
页码:305 / 307
页数:3
相关论文
共 50 条
  • [21] Functionalization and Chemical Modification of 2-Hydroxyethyl Methacrylate with Carboxylic Acid
    Nasirtabrizi, Mohammad Hossein
    Zargin, L.
    Khodabandlou, S.
    Rostamzadehmansor, S.
    E-JOURNAL OF CHEMISTRY, 2012, 9 (03) : 1135 - 1144
  • [22] Conformational and solvent effects in structural and spectroscopic properties of 2-hydroxyethyl methacrylate and acrylic acid
    Vettori, Irene
    Macchiagodena, Marina
    Pagliai, Marco
    Bassu, Gavino
    Fratini, Emiliano
    Baglioni, Piero
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 360
  • [23] Negative-working photoresist of methacrylate polymers based on the transesterification of the 2-hydroxyethyl group in the presence of an acid
    Lee, J
    Aoai, T
    Kondo, S
    Miyagawa, N
    Takahara, S
    Yamaoka, T
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (11) : 1858 - 1867
  • [24] Macroscopic and microscopic investigations of 2-hydroxyethyl methacrylate based molecularly imprinted networks.
    Oral, E
    Peppas, NA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U316 - U316
  • [25] Solvent Effects on Radical Copolymerization Kinetics of 2-Hydroxyethyl Methacrylate and Butyl Methacrylate
    Idowu, Loretta A.
    Hutchinson, Robin A.
    POLYMERS, 2019, 11 (03)
  • [26] Biocompatible and degradable poly(2-hydroxyethyl methacrylate) based polymers for biomedical applications
    Zhang, Yi
    Chu, Dafeng
    Zheng, Mengyao
    Kissel, Thomas
    Agarwal, Seema
    POLYMER CHEMISTRY, 2012, 3 (10) : 2752 - 2759
  • [27] 2-Hydroxyethyl methacrylate inflammatory effects in human gingival fibroblasts
    Di Nisio, C.
    Zara, S.
    Cataldi, A.
    di Giacomo, V.
    INTERNATIONAL ENDODONTIC JOURNAL, 2013, 46 (05) : 466 - 476
  • [28] INTRAOCULAR BIOCOMPATIBILITY OF HYDROXYETHYL METHACRYLATE AND METHACRYLIC-ACID COPOLYMER PARTIALLY HYDROLYZED POLY(2-HYDROXYETHYL METHACRYLATE)
    SMETANA, K
    SULC, J
    KRCOVA, Z
    PITROVA, S
    JOURNAL OF BIOMEDICAL MATERIALS RESEARCH, 1987, 21 (10): : 1247 - 1253
  • [29] Studies of the Molecular Recognition Abilities of Gallic Acid-imprinted Polymer Prepared Using a Molecular Imprinting Technique
    Pardeshi, Sushma
    Dhodapkar, Rita
    Kumar, Anupama
    ADSORPTION SCIENCE & TECHNOLOGY, 2012, 30 (01) : 23 - 34
  • [30] Preparation and characterization of the poly(2-hydroxyethyl methacrylate)–salicylic acid conjugate
    Roman Jantas
    Lucyna Herczyńska
    Polymer Bulletin, 2010, 64 : 459 - 469