Recent advances in the synthesis of monolithic metal-organic frameworks

被引：91

作者：

Duan, Chongxiong ^{[1
,3
]}

Yu, Yi ^{[2
]}

Li, Jingjing ^{[1
,3
]}

Li, Libo ^{[2
]}

Huang, Bichun ^{[4
]}

Chen, Dongchu ^{[1
,3
]}

Xi, Hongxia ^{[2
]}

机构：

[1] Foshan Univ, Sch Mat Sci & Hydrogen Engn, Foshan 528231, Peoples R China

[2] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

[3] Guangdong Key Lab Hydrogen Energy Technol, Foshan 528000, Peoples R China

[4] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China

来源：

SCIENCE CHINA-MATERIALS | 2021年 / 64卷 / 06期

基金：

中国国家自然科学基金;

关键词：

metal-organic frameworks; monolithic structure; synthetic strategies; industrial practicability;

D O I：

10.1007/s40843-020-1585-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Although considerable achievements have been realized in recent years with respect to the syntheses of metal-organic frameworks (MOFs), majority of the developed MOFs are in the form of polydisperse microcrystalline powders, which cause dustiness, abrasion, and clogging and decrease pressure when used in industrial applications. Monolithic MOFs overcome these drawbacks and exhibit various promising characteristics. In this review, we present the recent advances associated with monolithic MOFs based on metal centers and a brief outline of the most prominent examples. Furthermore, the challenges and prospects associated with monolithic MOFs in terms of large-scale production and engineering applicability are analyzed based on our knowledge to conclude this review.

引用

页码：1305 / 1319

页数：15

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