Packed and Monolithic Reactors for the Dry Reforming of Methane: Ni Supported on γ-Al2O3 Promoted by Ru

被引：4

作者：

Luisetto, I. ^{[1
]}

Sarno, C. ^{[2
]}

De Felicis, D. ^{[3
]}

Basoli, F. ^{[4
]}

Battocchio, C. ^{[1
]}

Tuti, S. ^{[1
]}

Bemporad, E. ^{[3
]}

Licoccia, S. ^{[2
]}

Di Bartolomeo, E. ^{[2
]}

机构：

[1] Roma Tre Univ, Dept Sci, Via Vasca Navale 79, I-00146 Rome, Italy

[2] Tor Vergata Univ, Dept Chem Sci & Technol, Via Ric Sci, I-00133 Rome, Italy

[3] Roma Tre Univ, Dept Engn, Via Vasca Navale 79, I-00146 Rome, Italy

[4] Campus Biomed Roma Univ, Dept Engn, Via Alvaro del Portillo 21, I-00128 Rome, Italy

来源：

ADVANCED SCIENCE LETTERS | 2017年 / 23卷 / 06期

关键词：

Ni/Al2O3; NiRu/Al2O3; Structured Catalyst; Dry Reforming of Methane; Carbon Deposition; CATALYSTS;

D O I：

10.1166/asl.2017.9085

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The Dry reforming of methane (DRM) is as an efficient way for CH4 and CO2 valorisation because the produced syn-gas has an H-2/CO ratio equal to that suitable for the synthesis of oxygenated hydrocarbons and synthetic fuels. The development of Ni (10 wt%) based structured and unstructured catalysts promoted by a small amount of Ru (0.5 wt%) has been investigated. Unstructured catalysts were prepared by wet impregnation method and a combination of wash coating-wet impregnation methods was used for cordierite monoliths. Ru promoted catalyst (Ni-Ru) was remarkable active showing higher reactant conversions and H-2/CO ratio compared with Ni catalyst. Ni-Ru monolith was initially much more active than monometallic Ni stating the positive effect of Ru on maintaining Ni reduced. Reaching steady state condition, Ni rapidly deactivated due to carbon formation, whereas Ni-Ru monolith remained stable confirming that Ru behaves as an efficient and cheap promoter of Ni for DRM.

引用

页码：5977 / 5979

页数：3

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