Bis(2,2′-bipyridine N,N′-dioxide)bis(tricyanomethanido)manganese(II)

被引：3

作者：

Luo, Jun ^{[1
]}

Yang, Feng ^{[1
]}

Qiu, Li-Juan ^{[1
]}

Wang, Xin-Xia ^{[2
]}

Liu, Bao-Shu ^{[1
]}

机构：

[1] Second Mil Med Univ, Sch Pharm, Shanghai 200433, Peoples R China

[2] Second Mil Med Univ, Eastern Hepatobiliary Surg Hosp, Dept Pharm, Shanghai 200438, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; TRICYANOMETHANIDE; C(CN)(3)(-); TCM(-);

D O I：

10.1107/S1600536809013828

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Mn(C4N3)(2)(C10H8N2O2)(2)], the Mn-II atom lies on an inversion center and is coordinated by two 2,2'-bipyridine N,N'-dioxide (dpdo) molecules and two tricyanomethanide (tcm) ligands to form a distorted octahedral geometry. Weak intermolecular C-H center dot center dot center dot O or C-H center dot center dot center dot N hydrogen bonds, involving either the O atom of the dpdo molecule and the pyridyl H atom, or the N atom of the tcm anion and the pyridyl H atom, result in the formation of a three-dimensional network structure.

引用

页码：M547 / U761

页数：11

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