Triple bond to lead:: Synthesis and characterization of the plumbylidyne complex trans-[Br(PMe3)4MoPb-C6H3-2,6-Trip2]

被引：65

作者：

Filippou, AC ^{[1
]}

Rohde, H ^{[1
]}

Schnakenburg, G ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 17期

关键词：

density functional calculations; Group; 14; elements; lead; molybdenum; triple bonds;

D O I：

10.1002/anie.200353477

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mine's a triple! The reaction of cis-[Mo(N2) 2(PMe3)4) with (Pb(Br)R)2 affords the red-brown plumbylidyne complex 1 (see scheme), which is the first compound to feature a triple bond to a main-group element of the sixth row. The molecular structure of 1 reveals a very short Mo-Pb bond of 2.5495(8) Å and a near linear coordination at the lead atom (Mo-Pb-Caryl 177.8(2)°) (R = 2,6-Trip2-C6H3, Trip = 2,4,6-iPr 3-C6H2).

引用

页码：2243 / 2247

页数：5

共 25 条

[1] Tungsten-lead triple bonds:: Syntheses, structures, and coordination chemistry of the plumbylidyne complexes trans-[X(PMe3)4WPb(2,6-Trip2C6H3)]
Filippou, AC
Weidemann, N
Schnakenburg, G
Rohde, H
Philippopoulos, AI
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (47) : 6512 - 6516
[2] Activation of aryl germanium(II) chlorides by [Mo(PMe3)6] and [W(η2-CH2PMe2)H(PMe3)4]:: A new route to metal-germanium triple bonds
Filippou, Alexander C.
Weidemann, Nils
Philippopoulos, Athanassios I.
Schnakenburg, Gregor
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) : 5987 - 5991
[3] Theoretical investigation of triple bond in molybdenum complexes trans-[X(PMe3)4 MoE(Mes)] (X = F, Cl, Br, I; E = Si, Ge, Sn, Pb): A DFT study
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Patidar, Pankaj
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[4] Theoretical Elucidation of the Mechanism of Cleavage of the Aromatic C-C Bond in Quinoxaline by a Tungsten-Based Complex [W(PMe3)4(η2-CH2PMe2)H]
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[5] Formation of a cationic alkylidene complex via formal hydride abstraction: synthesis and structural characterization of [W(PMe3)4(η2-CHPMe2)H]X (X = Br, I)
Sattler, Aaron
Parkin, Gerard
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[6] Synthesis and characterization of the monomeric sterically encumbered diaryls E{C6H3-2,6-(C6H3-2,6-Pri2)2}2 (E = Ge, Sn, or Pb)
Spikes, Geoffrey H.
Peng, Yang
Fettinger, James C.
Power, Philip P.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (06): : 1005 - 1010
[7] Stereoselective synthesis and reactivity of cis- and trans-dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand.: X-ray molecular structures of cis-[{Mo(CO)2(NO)}2{μ-(η5-C5H3)2(SiMe2)2}], trans-[{Mo(CO)(NO)(CNtBu)}2{μ-(η5-C5H3)2(SiMe2)2}], cis-[{Mo2(CO)3(NO)2(PMe3)}{μ-(η5-C5H3)2(SiMe2)2}] and trans-[{Mo(NO)(CNtBu)2}2{μ-(η5-C5H3)2(SiMe2)2}]
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[8] Synthesis and characterization of the gold(I) tris(ethylene) complex [AU(C2H4)3][SbF6]
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Fianchini, Mauro
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) : 556 - 559
[9] Synthesis and characterization of d2-molybdenum imido complexes containing coordinated dithio-ligands.: MO rationalization of the preferential isomer formation of Mo(N-2,4,6-Me3C6H2)(S2COMe)Cl(PMe3)2
Montilla, F
Pastor, A
Galindo, A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 587 (01) : 127 - 131
[10] Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2
Bukhryakov, Konstantin V.
Schrock, Richard R.
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Becker, Jonathan
ORGANIC LETTERS, 2017, 19 (10) : 2607 - 2609

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