Exciplexes in highly excited triplet states

被引：3
|
作者：
Alfimov, M. V. [1 ,3 ]
Plotnikov, V. G. [1 ,3 ]
Smirnov, V. A. [2 ,3 ]
Artyukhov, V. Ya. [3 ]
Maier, G. V. [3 ]
机构：
[1] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[3] Tomsk State Univ, Tomsk 634050, Russia
来源：
HIGH ENERGY CHEMISTRY | 2014年 / 48卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
ABSORPTION-SPECTRA;
D O I：
10.1134/S0018143914030023
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A mechanism of energy transfer from highly excited triplet aromatic molecules has been developed, which involves a stage of formation of an exciplex between a highly excited energy-donor molecule and an unexcited energy-acceptor molecule. Interpretation of the experimental data on the shape and the intensity of triplet-triplet absorption bands and the energy transfer probability is presented. In this interpretation, the results of quantum-chemical calculations of the energies of highly excited triplet states of toluene and benzene molecules are used.
引用
收藏
页码：174 / 179
页数：6
相关论文
共 50 条
  • [21] Sensitization of singlet oxygen via encounter complexes and via exciplexes of ππ* triplet excited sensitizers and oxygen
    Zahra Mehrdad
    Astrid Noll
    Erich-Walter Grabner
    Reinhard Schmidt
    Photochemical & Photobiological Sciences, 2002, 1 : 263 - 269
  • [22] Sensitization of singlet oxygen via encounter complexes and via exciplexes of ππ* triplet excited sensitizers and oxygen
    Mehrdad, Z
    Noll, A
    Grabner, EW
    Schmidt, R
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2002, 1 (04) : 263 - 269
  • [23] QUENCHING OF TRIPLET-STATES OF PHENAZINE AND ITS MONOBENZO, DIBENZO, AND TETRABENZO DERIVATIVES AND OF THEIR TRIPLET EXCIPLEXES WITH DIMETHYLANILINE BY OXYGEN
    OSIPOV, VV
    USACHEVA, MN
    DILUNG, II
    HIGH ENERGY CHEMISTRY, 1985, 19 (06) : 419 - 421
  • [24] TRIPLET EXCIPLEXES OF CHLORANIL WITH METHYLATED BENZENES
    LEVIN, PP
    KUZMIN, VA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1986, 35 (06): : 1303 - 1305
  • [25] Selective quenching of triplet excited states of pteridines
    M. Paula Denofrio
    Peter R. Ogilby
    Andrés H. Thomas
    Carolina Lorente
    Photochemical & Photobiological Sciences, 2014, 13 : 1058 - 1065
  • [26] Utilization of triplet excited states in organic semiconductors
    Song Guo
    Shujuan Liu
    Kenneth Yin Zhang
    Wei Huang
    Qiang Zhao
    Journal of Semiconductors, 2019, 40 (07) : 13 - 15
  • [27] PROPERTIES OF TRIPLET EXCIPLEXES OF PORPHYRIN COMPOUNDS
    KAPINUS, EI
    STARYI, VP
    DILUNG, II
    DOKLADY AKADEMII NAUK SSSR, 1981, 261 (04): : 907 - 911
  • [28] Access to the triplet excited states of organic chromophores
    Sasikumar, Devika
    John, Athira T.
    Sunny, Jeswin
    Hariharan, Mahesh
    CHEMICAL SOCIETY REVIEWS, 2020, 49 (17) : 6122 - 6140
  • [29] TRIPLET EXCITED STATES OF PYRIMIDINES AND PURINES IN SOLUTION
    HAYON, E
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1969, (SEP): : P187 - &
  • [30] Singlet and triplet valence excited states of pyrimidine
    Fischer, G
    Cai, ZL
    Reimers, JR
    Wormell, P
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (17): : 3093 - 3106
12345