Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks

被引：86
|
作者：
Mlinar, Anton N. [1 ]
Keitz, Benjamin K. [2 ]
Gygi, David [2 ]
Bloch, Eric D. [2 ]
Long, Jeffrey R. [2 ]
Bell, Alexis T. [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
ACS CATALYSIS | 2014年 / 4卷 / 03期
关键词：
metal-organic frameworks; catalysis; oligomerization; propene; nickel; HYDROGEN STORAGE; H-2; ADSORPTION; CARBON-DIOXIDE; ETHYLENE; DIMERIZATION; CATALYSTS; NI; POLYMER; COMPLEX; ETHENE;
D O I：
10.1021/cs401189a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two Ni2+-containing metal-organic frameworks, Ni-2(dobdc) and Ni-2(dobpdc), are shown to be active for the oligomerization of propene in the gas phase. The metal-organic frameworks exhibit activity comparable to Ni2+-exchanged aluminosilicates but maintain high selectivity for linear oligomers. Thus, these frameworks should enable the high yielding synthesis of linear propene oligomers for use in detergent and diesel fuel applications.
引用
收藏
页码：717 / 721
页数：5
相关论文
共 50 条
  • [41] Selective adsorption of volatile organic compounds in metal-organic frameworks (MOFs)
    Siu, Benjamin
    Chowdhury, Aminur Rashid
    Yan, Ziwen
    Humphrey, Simon M.
    Hutter, Tanya
    COORDINATION CHEMISTRY REVIEWS, 2023, 485
  • [42] Emissive lead(II) benzenedicarboxylate metal-organic frameworks
    Peedikakkal, Abdul Malik P.
    Qamar, Mohammad
    JOURNAL OF CHEMICAL SCIENCES, 2018, 130 (05)
  • [43] Emissive lead(II) benzenedicarboxylate metal-organic frameworks
    Abdul Malik P Peedikakkal
    Mohammad Qamar
    Journal of Chemical Sciences, 2018, 130
  • [44] Syntheses and crystal structures of two new nickel (II) metal-organic frameworks with a polydentate ligand
    Jia-Ming Li
    Kun-Huan He
    Zhong-Feng Shi
    Hui-Yuan Gao
    Yi-Min Jiang
    Journal of Porous Materials, 2016, 23 : 1679 - 1685
  • [45] Syntheses and crystal structures of two new nickel (II) metal-organic frameworks with a polydentate ligand
    Li, Jia-Ming
    He, Kun-Huan
    Shi, Zhong-Feng
    Gao, Hui-Yuan
    Jiang, Yi-Min
    JOURNAL OF POROUS MATERIALS, 2016, 23 (06) : 1679 - 1685
  • [46] Nickel(II) oxide nanostructure derived from metal-organic frameworks and its adsorption capability
    Ru, Shuai
    Xu, Lina
    Xiao, Hongping
    Li, Xinhua
    MATERIALS RESEARCH EXPRESS, 2016, 3 (11):
  • [47] Selective tandem catalysis by metal nanoclusters encapsulated in metal-organic frameworks
    Li, Xinle
    Xiao, Chaoxian
    Goh, Tian Wei
    Huang, Wenyu
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [48] Metal-Organic Frameworks and Metal-Organic Cages - A Perspective
    Pilgrim, Ben S.
    Champness, Neil R.
    CHEMPLUSCHEM, 2020, 85 (08): : 1842 - 1856
  • [49] Synthesis and electrochemical properties of two cobalt(II) and nickel(II) metal-organic frameworks for excellent performance supercapacitors
    Zhu, Hongli
    Wang, Xiangting
    Yang, Jie
    Xu, Pengye
    Ling, Liaoxuan
    Jiao, Jingjing
    Wang, Xiao-Qing
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321
  • [50] High-throughput screening of metal-organic frameworks for kinetic separation of propane and propene
    Pramudya, Yohanes
    Bonakala, Satyanarayana
    Antypov, Dmytro
    Bhatt, Prashant M.
    Shkurenko, Aleksander
    Eddaoudi, Mohamed
    Rosseinsky, Matthew J.
    Dyer, Matthew S.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (40) : 23073 - 23082
12345