A novel method for synthesizing 4,4′-bis(hydroxymethyl)-2,2′-bipyridine

被引：0

作者：

Su, ZM

Chen, LH

Wu, LX

Xu, HB

Zhu, DX

Wang, RS

机构：

[1] NE Normal Univ, Dept Chem, Funct Mat Inst, Changchun 130024, Peoples R China

[2] Jilin Univ, Inst Theoret Chem, Natl Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2002年 / 18卷 / 03期

关键词：

4 4 '-bis(hydroxymethyl)-2,2 '-bipyridine; synthesis; 4,4-dimethyl-2,2 '-bipyridine;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There are several paths for synthesizing 4.4'-bis(hydroxymethyl)-2.2'-bipyridine. but most of them need strict experimental conditions that are not easy to be overcome. We designed a simple way to prepare this product via the oxidation of 4.4'-bismethyl-2,2'-bipyridine, followed by esterification and reduction. The yield increases and the reaction conditions become genial in contrast to those of other methods. The molecular structure of the final product was confirmed by means of elemental analysis, IR. H-1 NMR and MS spectra.

引用

页码：345 / 347

页数：3

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[1] APPLICATION OF THE ENERGY-GAP LAW TO NONRADIATIVE, EXCITED-STATE DECAY [J].