Self assembly of carboxylate/alcoholate functionalized ring-shape phosphomolybdates

被引：27

作者：

Yang, Donghui ^{[1
]}

Liang, Yanfen ^{[1
]}

Ma, Pengtao ^{[1
]}

Li, Suzhi ^{[2
]}

Wang, Jingping ^{[1
]}

Niu, Jingyang ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate, Kaifeng 475004, Henan, Peoples R China

[2] Shangqiu Normal Univ, Coll Chem & Chem Engn, Engn Res Ctr Funct Mat Preparat, Shangqiu 476000, Henan, Peoples R China

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 34期

基金：

中国国家自然科学基金;

关键词：

POLYOXOMETALATE-DIPHOSPHATE COMPLEXES; MOLYBDATE-CATALYZED HYDROLYSIS; ORGANIC-INORGANIC MATERIALS; BUILDING-BLOCKS; STRUCTURAL-CHARACTERIZATION; OXOTHIOMOLYBDENUM WHEELS; MOLECULAR MATERIALS; CRYSTAL-STRUCTURES; DFT CALCULATIONS; AMINO-ACIDS;

D O I：

10.1039/c4ce00580e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a simple and efficient approach to incorporate organic groups into polymolybdates by reaction of H3PO3 with Na2MoO4 center dot 2H(2)O/(NH4)(6)Mo7O24 center dot 4H(2)O and organic components in aqueous medium. Carboxylate and alcoholate ligands were covalently attached to the [HPMo6O21](2-) cluster to generate a series of inorganic-organic hybrid phosphomolybdates. Depending on the successful synthesis of these structures, it could be possible to obtain a variety of these hybrids through rational structural design using ligand control, which is rare in traditional "one-pot" polyoxometalate (POM) synthesis.

引用

页码：8041 / 8046

页数：6

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