A Highly Stable 3D Acentric Zinc Metal-Organic Framework Based on Two Symmetrical Flexible Ligands: High Second-Harmonic-Generation Efficiency and Tunable Photoluminescence

被引：34
作者：
Guo, Jin-Shuang [1 ]
Xu, Gang [1 ]
Jiang, Xiao-Ming [1 ]
Zhang, Ming-Jian [1 ]
Liu, Bin-Wen [1 ]
Guo, Guo-Cong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 09期
关键词：
OPTICAL-PROPERTIES; COMPLEX;
D O I：
10.1021/ic500315z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D metal-organic framework (MOF), [Zn(BPHY)(SA)](n) (1; BPHY = 1,2-bis(4-pyridyl)-hydrazine, H(2)SA = succinic acid), which crystallizes in a noncentrosysmmetric space group (Cc), has been solvothermally obtained and testified to be a good nonlinear-optical material with the largest second-harmonic-generation response among the known MOFs based on sysmmetric ligands and high stability. Ultraviolet-to-visible tunable emission for 1 is observed.
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收藏
页码：4278 / 4280
页数：3
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