Solvatochromism of heteroaromatic compounds:: XXIIII.1: Reversible specific solvatochromic effect in the IR spectra of 2-nitrophenol and 2,4,6-trinitrophenol

被引：7

作者：

Vokin, AI ^{[1
]}

Gavrilova, GA ^{[1
]}

Shulunova, AM ^{[1
]}

Krivoruchka, IG ^{[1
]}

Aksamentova, TN ^{[1
]}

Turchaninov, VK ^{[1
]}

机构：

[1] RAS, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 02期

关键词：

D O I：

10.1023/B:RUGC.0000025510.90789.3c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Nitrophenol and 2,4,6-trinitrophenol form with protophilic solvents complexes with a bifurcate (three-center) hydrogen bond. Their O-H stretching vibration frequencies nonlinearly and unsteadily vary with the H-bond acceptor ability of the medium, which is a spectroscopic evidence for three-center H-complex formation.

引用

页码：239 / 249

页数：11

共 39 条

[31]

PREZHDO VV, 1981, ZH OBSHCH KHIM+, V51, P927

[32] DIPOLE MOMENT AND INFRA-RED STUDIES OF SOLVENT EFFECTS ON INTRAMOLECULAR HYDROGEN BONDING .2. NITROPHENOLS AND NITRONAPHTHOLS [J].

RICHARDS, JH ;

WALKER, S .

TRANSACTIONS OF THE FARADAY SOCIETY, 1961, 57 (03) :406-&

[33]

RUMYNSKAYA IG, 1982, OPT SPEKTROSK+, V53, P589

[34] SOME EFFECTS OF INTRAMOLECULAR HYDROGEN-BONDING ON VIBRATIONAL-SPECTRA [J].

SCHREIBER, VM .

JOURNAL OF MOLECULAR STRUCTURE, 1989, 197 :73-85

[35] IR MATRIX-ISOLATION AND MNDO/PM3 STUDIES OF ORTHO-SUBSTITUTED PHENOLS WITH INTRAMOLECULAR H-BONDS [J].

SHREIBER, V ;

KOLL, A ;

KULBIDA, A ;

MAJERZ, I .

JOURNAL OF MOLECULAR STRUCTURE, 1995, 348 :365-368

[36] Intramolecular interactions in ortho-substituted phenols: survey of DFT-B3LYP calculated data [J].

Simperler, A ;

Lampert, H ;

Mikenda, W .

JOURNAL OF MOLECULAR STRUCTURE, 1998, 448 (2-3) :191-199

[37] GEOMETRY OF THE N-H-O=C HYDROGEN-BOND .2. 3-CENTER (BIFURCATED) AND 4-CENTER (TRIFURCATED) BONDS [J].

TAYLOR, R ;

KENNARD, O ;

VERSICHEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (01) :244-248

[38]

TAYLOR R, 1984, ACCOUNTS CHEM RES, V17, P320, DOI 10.1021/ar00105a004

[39]

TURCHANINOV VK, 2001, ZH OBSHCH KHIM, V71, P261

← 1 2 3 4 →