Solvatochromism of heteroaromatic compounds:: XXIIII.1: Reversible specific solvatochromic effect in the IR spectra of 2-nitrophenol and 2,4,6-trinitrophenol

被引：7

作者：

Vokin, AI ^{[1
]}

Gavrilova, GA ^{[1
]}

Shulunova, AM ^{[1
]}

Krivoruchka, IG ^{[1
]}

Aksamentova, TN ^{[1
]}

Turchaninov, VK ^{[1
]}

机构：

[1] RAS, Favorskii Irkutsk Inst Chem, Siberian Div, Irkutsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 02期

关键词：

D O I：

10.1023/B:RUGC.0000025510.90789.3c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Nitrophenol and 2,4,6-trinitrophenol form with protophilic solvents complexes with a bifurcate (three-center) hydrogen bond. Their O-H stretching vibration frequencies nonlinearly and unsteadily vary with the H-bond acceptor ability of the medium, which is a spectroscopic evidence for three-center H-complex formation.

引用

页码：239 / 249

页数：11

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