Selective synthesis of 2,5-bis(aminomethyl) furan via enhancing the catalytic dehydrationhydrogenation of 2,5-diformylfuran dioxime

被引：48

作者：

Xu, Yongming ^{[1
,2
]}

Jia, Xiuquan ^{[1
]}

Ma, Jiping ^{[1
]}

Gao, Jin ^{[1
]}

Xia, Fei ^{[1
,2
]}

Li, Xiaofang ^{[1
,2
]}

Xu, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

GREEN CHEMISTRY | 2018年 / 20卷 / 12期

基金：

中国国家自然科学基金;

关键词：

REDUCTIVE AMINATION; AEROBIC OXIDATION; COBALT CATALYSTS; VALERIC BIOFUEL; Y-ZEOLITE; ACID; HYDROGENATION; AMMONIA; BIOMASS; AMINES;

D O I：

10.1039/c8gc00947c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,5-Bis(aminomethyl)furan as a promising monomer was efficiently synthesized in 94.1% yield from biomass-derived 2,5-diformylfuran dioxime. The high selectivity is likely to be a result of the controlled reaction pathway over Rh/HZSM-5, which enhanced the sequence of the dehydration-hydrogenation of 2,5-diformylfuran dioxime owing to the surface acidity on the HZSM-5 support.

引用

收藏

页码：2697 / 2701

页数：5

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