Selective Synthesis of Manganese Dioxide Polymorphs by the Hydrothermal Treatment of Aqueous KMnO4 Solutions

被引：11
作者：
Egorova, A. A. [1 ]
Bushkova, T. M. [1 ]
Kolesnik, I. V. [2 ]
Yapryntsev, A. D. [1 ]
Kottsov, S. Yu. [1 ,2 ]
Baranchikov, A. E. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
hydrothermal synthesis; potassium permanganate; cryptomelane; birnessite; pyrolusite; hollandite; SOLID-STATE SYNTHESIS; ALPHA-MNO2; NANOWIRES; PHASE-TRANSFORMATION; MNO2; ELECTRODE; NANOSTRUCTURES; BETA-MNO2; CRYPTOMELANE; BIRNESSITE; SPECTRA;
D O I：
10.1134/S0036023621020066
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrothermal treatment of neutral and acidified KMnO4 solutions at concentration of 0.037-0.093 mol/L and temperature of 120, 170, and 220 degrees C for 24 h leads to selective synthesis of three different manganese dioxide modifications: alpha-MnO2, delta-MnO2, and beta-MnO2. The temperature of hydrothermal treatment and medium acidity has been shown to affect considerably the phase composition of KMnO4 reduction products and reaction yield. The obtained samples of MnO2 have been characterized by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and diffuse reflectance spectroscopy.
引用
收藏
页码：146 / 152
页数：7
相关论文
共 48 条
  • [1] [Anonymous], 2013, HDB HYDROTHERMAL TEC
  • [2] Formation Mechanisms of Nanocrystalline MnO2 Polymorphs under Hydrothermal Conditions
    Birgisson, Steinar
    Saha, Dipankar
    Iversen, Bo B.
    [J]. CRYSTAL GROWTH & DESIGN, 2018, 18 (02) : 827 - 838
  • [3] EPR Spectra and Distribution of Manganese Ions in Modified Fluorozirconate Glasses
    Brekhovskikh, M. N.
    Solodovnikov, S. P.
    Moiseeva, L., V
    Zhidkova, I. A.
    Denisov, G. L.
    Fedorov, V. A.
    [J]. INORGANIC MATERIALS, 2019, 55 (07) : 710 - 714
  • [4] Optical Properties and Electron Paramagnetic Resonance of MnO2-Doped Fluorozirconate Glasses
    Brekhovskikh, M. N.
    Batygov, S. Kh.
    Moiseeva, L. V.
    Solodovnikov, S. P.
    Zhidkova, I. A.
    Denisov, G. L.
    Fedorov, V. A.
    [J]. INORGANIC MATERIALS, 2018, 54 (11) : 1157 - 1161
  • [5] Vibrational spectroscopy of bulk and supported manganese oxides
    Buciuman, F
    Patcas, F
    Craciun, R
    Zahn, DRT
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (01) : 185 - 190
  • [6] Solid-State Synthesis of Lithium-Substituted Spinels Mg1-xLixMnO3-δ
    Buzanov, G. A.
    Simonenko, N. P.
    Zhizhin, K. Yu.
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (12) : 1482 - 1485
  • [7] Solid State Synthesis and Reversible Oxygen Capacity of Li/Mg Overstoichiometric Solid Solutions Based on the Spinel MgMnO3-δ
    Buzanov, G. A.
    Simonenko, N. P.
    Zhizhin, K. Yu.
    Kuznetsov, N. T.
    [J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (11) : 1335 - 1341
  • [8] Cao H., 2009, P INT C ADV FIB POL, V2, P1302, DOI [10.1002/chin.200523238, DOI 10.1002/CHIN.200523238]
  • [9] Understanding crystallization pathways leading to manganese oxide polymorph formation
    Chen, Bor-Rong
    Sun, Wenhao
    Kitchaev, Daniil A.
    Mangum, John S.
    Thampy, Vivek
    Garten, Lauren M.
    Ginley, David S.
    Gorman, Brian P.
    Stone, Kevin H.
    Ceder, Gerbrand
    Toney, Michael F.
    Schelhas, Laura T.
    [J]. NATURE COMMUNICATIONS, 2018, 9
  • [10] Fedosova S.P, 1975, GROWTH CRYSTALS, V9, P62
12345