Clay Catalyzed Reactions of Indole and its Methyl Derivatives with α, β-unsaturated Carbonyl Compounds

被引：0

作者：

Dasbasi, Teslima ^{[1
]}

Abdullah, Meysun I. ^{[2
]}

机构：

[1] Bozok Univ, Fac Sci & Arts, Dept Chem, TR-66200 Yozgat, Turkey

[2] Nigde Univ, Fac Sci & Arts, Dept Chem, TR-51200 Nigde, Turkey

来源：

CROATICA CHEMICA ACTA | 2014年 / 87卷 / 02期

关键词：

Michael addition; bisindolylester; trisindolylester; benzoazepine; K-10; montmorillonite; ELECTROPHILIC SUBSTITUTION; MICHAEL ADDITION; EFFICIENT; BIS(INDOLYL)METHANES; INHIBITORS; ALKALOIDS; FACILE; IODINE;

D O I：

10.5562/cca2285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrophilic substituons reactions of indole and 1-methylindole with methyl propiolate in the presence of K-10 montmorillonite were obtained the formation of the corresponding methyl 3,3-bis(indolyl)propanoates. The reaction of 1,3-dimethylindole with methyl propiolate was given methyl 3,3-bis(1,3-dimethyl-1H-indol-2-yl)propanoate, methyl 1,5-dimethyl-1H-benzo[b]azepine-3-carboxylate and methyl 3,3,3-tris(1,3-dimethyl-1H-indol-2-yl)propanoate. The reaction of 1,3-dimethylindole with 2-cyclopentenone was yielded a typical addition product, similarly the reaction of indole and 1-methylindole with 2-cyclopentenone were concluded the expected addition products only.

引用

页码：137 / 142

页数：6

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