Analysis of Dolomite of Balochistan (Pakistan) by Using X-Ray Fluorescence Spectroscopy (XFS), Simultaneous Differential Thermal Analysis (SDTA), Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC)

被引:0
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作者
Jabeen, Salma [1 ]
Raza, Syed Mohsin [1 ]
Mehmood, Khalid [2 ]
Atiq, Shabbar [3 ]
Farooqi, Zia-Ul-Haq
机构
[1] Univ Balochistan, Dept Phys, Quetta, Pakistan
[2] Univ Balochistan, Inst Bio Chem, Quetta, Pakistan
[3] Pakistan Council Sci & Ind Res, Quetta, Pakistan
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2009年 / 31卷 / 01期
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We deciphered new methods for calculation of thermodynamic parameters from SDTA, TGA & DSC techniques. The stretching of ionic bonds between Mg++ and CO3- and Ca++ and CO3 respectively is conformed on TGA curve at a temperature of 427 degrees K. At 728 K, an ore of dolomite is decomposed due to release of carbon dioxide and carbon monoxide gases and the left over Substance is a mixture of MgO and CaO. The ionic bond breaking occurs at 723 degrees K After this, there is reshuffling of ions due to which MgO and CaO are produced at 816 degrees K and 835 K. respectively. The chemists have to think about the chemical processes to separate MgO, a refractory material, from CaO, after baking dolomite upto about 840 degrees K.
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页码:1 / 6
页数:6
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