Glycerol as solvent and hydrogen donor in transfer hydrogenation-dehydrogenation reactions

被引:137
作者
Wolfson, Adi [1 ]
Dlugy, Christina [1 ]
Shotland, Yoram [1 ]
Tavor, Dorith [1 ]
机构
[1] Sami Shamoon Coll Engn, Dept Chem Engn, Green Proc Ctr, IL-84100 Beer Sheva, Israel
关键词
Transfer hydrogenation-dehydrogenation; Catalysis; Glycerol; Green solvent; LIQUID-PHASE OXIDATION; REDUCTION;
D O I
10.1016/j.tetlet.2009.08.035
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Glycerol is employed successfully as a green solvent and hydrogen donor in catalytic transfer hydrogenation-dehydrogenation reactions. The glycerol donates hydrogen to various unsaturated organic compounds under mild reaction conditions and as a solvent, allows easy separation of products and catalyst recycling. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5951 / 5953
页数:3
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