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Glycerol as solvent and hydrogen donor in transfer hydrogenation-dehydrogenation reactions
被引:137
作者:
Wolfson, Adi
[1
]
Dlugy, Christina
[1
]
Shotland, Yoram
[1
]
Tavor, Dorith
[1
]
机构:
[1] Sami Shamoon Coll Engn, Dept Chem Engn, Green Proc Ctr, IL-84100 Beer Sheva, Israel
关键词:
Transfer hydrogenation-dehydrogenation;
Catalysis;
Glycerol;
Green solvent;
LIQUID-PHASE OXIDATION;
REDUCTION;
D O I:
10.1016/j.tetlet.2009.08.035
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Glycerol is employed successfully as a green solvent and hydrogen donor in catalytic transfer hydrogenation-dehydrogenation reactions. The glycerol donates hydrogen to various unsaturated organic compounds under mild reaction conditions and as a solvent, allows easy separation of products and catalyst recycling. (C) 2009 Elsevier Ltd. All rights reserved.
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页码:5951 / 5953
页数:3
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