Glycerol as solvent and hydrogen donor in transfer hydrogenation-dehydrogenation reactions

被引:137
作者
Wolfson, Adi [1 ]
Dlugy, Christina [1 ]
Shotland, Yoram [1 ]
Tavor, Dorith [1 ]
机构
[1] Sami Shamoon Coll Engn, Dept Chem Engn, Green Proc Ctr, IL-84100 Beer Sheva, Israel
关键词
Transfer hydrogenation-dehydrogenation; Catalysis; Glycerol; Green solvent; LIQUID-PHASE OXIDATION; REDUCTION;
D O I
10.1016/j.tetlet.2009.08.035
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Glycerol is employed successfully as a green solvent and hydrogen donor in catalytic transfer hydrogenation-dehydrogenation reactions. The glycerol donates hydrogen to various unsaturated organic compounds under mild reaction conditions and as a solvent, allows easy separation of products and catalyst recycling. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5951 / 5953
页数:3
相关论文
共 15 条
[1]  
Anderson P. G, 2008, MODERN REDUCTION MET
[2]  
[Anonymous], [No title captured]
[3]  
[Anonymous], 1999, ORGANIC REACTION MEC
[4]   Transition metal hydrides as active intermediates in hydrogen transfer reactions [J].
Bäckvall, JE .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 652 (1-2) :105-111
[5]   Unexpected performance of solid alkaline metal hydroxides in liquid phase oxidation of 1-phenylethanol [J].
Ben-Harush, Kfir ;
Wolfson, Adi ;
Herskowitz, Moti .
LETTERS IN ORGANIC CHEMISTRY, 2006, 3 (09) :664-667
[6]   CATALYTIC TRANSFER HYDROGENATION [J].
BRIEGER, G ;
NESTRICK, TJ .
CHEMICAL REVIEWS, 1974, 74 (05) :567-580
[7]   Liquid phase oxidation of glycerol over carbon supported gold catalysts [J].
Demirel-Gülen, S ;
Lucas, M ;
Claus, P .
CATALYSIS TODAY, 2005, 102 :166-172
[8]   Selective reduction of α-chloroketone to α-chloroalcohol using hydrogen transfer from alcohol over metal oxide catalysts [J].
Gotoh, K ;
Kubo, J ;
Ueda, W ;
Mori, T ;
Morikawa, Y .
CHEMISTRY LETTERS, 2003, 32 (12) :1132-1133
[9]   Nickel bromide as a hydrogen transfer catalyst [J].
Le Page, MD ;
James, BR .
CHEMICAL COMMUNICATIONS, 2000, (17) :1647-1648
[10]   Catalytic transfer hydrogenation of 2-butanone on MgO.: New active surface sites generated by treatment with chloroform [J].
Szöllösi, G ;
Bartók, M .
CATALYSIS LETTERS, 1999, 59 (2-4) :179-185