Operando X-ray absorption spectroscopy applied to battery materials at ICGM: The challenging case of BiSb's sodiation

被引：11

作者：

Darwiche, Ali ^{[1
]}

Murgia, Fabrizio ^{[1
]}

Fehse, Marcus ^{[2
,3
,4
]}

Mahmoud, Abdelfattah ^{[5
]}

Iadecola, Antonella ^{[6
]}

Belin, Stephanie ^{[7
]}

La Fontaine, Camille ^{[7
]}

Briois, Valerie ^{[7
]}

Hermann, Raphael P. ^{[8
]}

Fraisse, Bernard ^{[1
]}

Berthelot, Romain ^{[1
,2
,6
]}

Sougrati, Moulay Tahar ^{[1
,2
,6
]}

Monconduit, Laure ^{[1
,2
,6
]}

Stievano, Lorenzo ^{[1
,2
,6
]}

机构：

[1] Univ Montpellier, CNRS, ICGM, Montpellier, France

[2] CNRS, Alistore European Res Inst, Amiens, France

[3] Delft Univ Technol, Fac Appl Sci, Delft, Netherlands

[4] ESRF, Dubble Beamline, Grenoble, France

[5] Univ Liege, Inst Chem, GreenMat, CESAM, Liege, Belgium

[6] CNRS, Reseau Stockage Electrochim Energie RS2E, Amiens, France

[7] Synchrotron Soleil, Gif Sur Yvette, France

[8] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN USA

来源：

ENERGY STORAGE MATERIALS | 2019年 / 21卷

关键词：

X-ray absorption spectroscopy; Batteries; Energy materials; Electrode materials; Electrochemical mechanism; Operando measurements; LITHIUM-SULFUR BATTERY; LI-ION BATTERIES; NEGATIVE ELECTRODE MATERIAL; LONG-CYCLE LIFE; RECHARGEABLE LITHIUM; HIGH-CAPACITY; MECHANISM; SB; BI; DIFFRACTION;

D O I：

10.1016/j.ensm.2019.06.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray absorption spectroscopy (XAS) is a synchrotron-based, element-specific, short-range structural method largely used in the study of materials, already widely employed for the study of the electrochemical processes in battery systems. The high penetration of the X-rays makes XAS particularly suited for the study of battery materials under operando conditions using specifically developed in situ electrochemical cells. In this paper, the application of XAS to the study of battery materials carried out at Institut Charles Gerhardt Montpellier (France) will be outlined, illustrating the type of information provided by XAS. The challenging study of the sodiation of Bi0.50Sb0.50 followed individually and simultaneously at both metals will be also presented in order to highlight the typical advantages of this technique even when it is pushed at its technical limits.

引用

页码：1 / 13

页数：13

共 106 条

[1] Tracking Sodium-Antimonide Phase Transformations in Sodium-Ion Anodes: Insights from Operando Pair Distribution Function Analysis and Solid-State NMR Spectroscopy [J].