Synthesis and spectroscopic studies of the charge-transfer complexes of 2,3-diaminopyridine and π-electron acceptors

被引：21

作者：

Alqaradawi, SY ^{[1
]}

Nour, EM ^{[1
]}

机构：

[1] Qatar Univ, Coll Sci, Dept Chem, Doha, Qatar

来源：

SPECTROSCOPY LETTERS | 2004年 / 37卷 / 04期

关键词：

CT-complexes; 2,3-diaminopyridine; chloranil; TCNE; electronic spectra; infrared spectra;

D O I：

10.1081/SL-120039468

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The spectrophotometric properties of the charge transfer (CT)-complexes formed between 2,3-diaminopyridine (DAPY) and pi-acceptors tetrachloro-p-benzoquinone (chloranil) and tetracyanoethylene (TCNE) have been studied in chloroform. The stoichiometry of these CT-complexes is shown to be 1:1, (DAPY:chloranil) and 1:3 (DAPY:TCNE) forming complexes with the general formula [(DAPY)(chloranil)] and [(DAPY)(TCNE)(3)]. The two complexes were isolated as solids and further characterized by elemental analysis and infrared measurements.

引用

页码：337 / 345

页数：9