Cobalt(III)-catalysed C-H allylation with vinylaziridines

被引：24
作者：
Kong, Lingyu [1 ]
Biletskyi, Bohdan [1 ]
Nuel, Didier [1 ]
Clavier, Herve [1 ]
机构：
[1] Aix Marseille Univ, CNRS, Cent Marseille, ISm2 UMR 7313, F-13397 Marseille, France
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 10期
关键词：
BOND FUNCTIONALIZATION; COBALT CATALYSIS; ACTIVATION; ARENES; AMIDATION; COMPLEX; OLEFINS; CARBON; RINGS; TOOL;
D O I：
10.1039/c8qo00173a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cobalt-catalysed C-H allylation of aromatic and heteroaromatic compounds with vinylaziridines is described. This transformation occurring under mild reaction conditions proceeds through C-H activation, carbon-carbon double bond insertion and beta-nitrogen elimination. Its scope and limitations have been investigated and a synthetic application of products has been achieved.
引用
收藏
页码：1600 / 1603
页数：4
相关论文
共 50 条
  • [31] Mild Cobalt(III)-Catalyzed C-H Hydroarylation of Conjugated C=C/C=O Bonds
    Li, Jie
    Zhang, Zhao
    Ma, Wenbo
    Tang, Mengyao
    Wang, Dawei
    Zou, Liang-Hua
    ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (10) : 1717 - 1724
  • [32] Rhodium(III)-catalyzed C-H/C-C activation sequence: vinylcyclopropanes as versatile synthons in direct C-H allylation reactions
    Wu, Jia-Qiang
    Qiu, Zhi-Ping
    Zhang, Shang-Shi
    Liu, Jing-Gong
    Lao, Ye-Xing
    Gu, Lian-Quan
    Huang, Zhi-Shu
    Li, Juan
    Wang, Honggen
    CHEMICAL COMMUNICATIONS, 2015, 51 (01) : 77 - 80
  • [33] Cobalt(III)-Catalyzed C-H Alkynylation with Bromoalkynes under Mild Conditions
    Sauermann, Nicolas
    Gonzalez, Maria J.
    Ackermann, Lutz
    ORGANIC LETTERS, 2015, 17 (21) : 5316 - 5319
  • [34] Amide-Directed Cobalt(III)-Catalyzed C-H Amidation of Ferrocenes
    Huang, Dan-Ying
    Yao, Qi-Jun
    Zhang, Shuo
    Xu, Xue-Tao
    Zhang, Kun
    Shi, Bing-Feng
    ORGANIC LETTERS, 2019, 21 (04) : 951 - 954
  • [35] Cobalt(III)-Catalyzed C-H Bond Amidation with Isocyanates
    Hummel, Joshua R.
    Ellman, Jonathan A.
    ORGANIC LETTERS, 2015, 17 (10) : 2400 - 2403
  • [36] Cobalt-catalyzed multisubstituted allylation of the chelation-assisted C-H bond of (hetero)arenes with cyclopropenes
    Ramachandran, Kuppan
    Anbarasan, Pazhamalai
    CHEMICAL SCIENCE, 2021, 12 (40) : 13442 - 13449
  • [37] Transition-metal-catalyzed C-H allylation reactions
    Dutta, Subhabrata
    Bhattacharya, Trisha
    Werz, Daniel B.
    Maiti, Debabrata
    CHEM, 2021, 7 (03): : 555 - 605
  • [38] Recent Advances in the High-Valent Cobalt-Catalyzed C-H Functionalization of N-Heterocycles
    Chandra, Devesh
    Manisha
    Sharma, Upendra
    CHEMICAL RECORD, 2022, 22 (03)
  • [39] Catalytic C-H Allylation and Benzylation of Pyrazoles
    Bae, Seri
    Jang, Ha-Lim
    Jung, Haeun
    Joo, Jung Min
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (01) : 690 - 697
  • [40] Zinc catalysed electrophilic C-H borylation of heteroarenes
    Grundy, Matthew E.
    Yuan, Kang
    Nichol, Gary S.
    Ingleson, Michael J.
    CHEMICAL SCIENCE, 2021, 12 (23) : 8190 - 8198
12345