Trialkyl tin salts of polyoxometalates: Synthesis and characterization of [α-SiW12O40][(CH3)3Sn(DMSO)2]4•2DMSO

被引：15

作者：

Legagneux, Nicolas ^{[1
]}

Jeanneau, Erwann ^{[2
]}

Basset, Jean-Marie ^{[1
]}

Lefebvre, Frederic ^{[1
]}

机构：

[1] ESCPE Lyon, Chim Organometall Surface Lab Chim, UMR C2P2 5265, CNRS,UCBL, F-69616 Villeurbanne, France

[2] Ctr Diffractometr Henri Longchambon UCBL, F-69616 Villeurbanne, France

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 921卷 / 1-3期

关键词：

Alkyltin; Heteropolyoxometalates; X-ray diffraction; Sn-119; NMR; SURFACE ORGANOMETALLIC CHEMISTRY; CRYSTAL-STRUCTURE; X-RAY; MOSSBAUER-SPECTRA; DERIVATIVES; CATALYSIS; ACIDS; NMR; COMPLEXES; H3PW12O40;

D O I：

10.1016/j.molstruc.2009.01.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tetramethyl tin reacts with dodecatungstosilicic acid H4SiW12O40 in anhydrous DMSO with evolution of methane to yield the trimethyl tin salt of the heteropolyoxometalate [alpha-SiW12O40][(CH3)(3)Sn(DMSO)(2)](4)center dot 2DMSO. The structure has been determined by X-ray diffraction and shows that there is no direct bond between the polyoxometalate and the tin complex. Sn-119 NMR indicates that tin has quite the same coordination in the solid state and in DMSO solution. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：300 / 306

页数：7

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