Synthesis and structure of a five-coordinate organochromium(III) thiolate complex from a chromium(II) alkyl precursor

被引：28
作者：
Fryzuk, MD
Leznoff, DB
Rettig, SJ
机构：
[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 23期
关键词：
D O I：
10.1021/om970574l
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the Cr(II) methyl complex, CrMe[N(SiMe2CH2PPh2)(2)], with diphenyl disulfide (PhSSPh) leads to the formation of the five-coordinate, paramagnetic complex CrMe(SPh)[N(SiMe2CH2PPh2)(2)] by an overall one-electron oxidation. The complex is unusual in that the phenyl thiolate moiety is terminal and does not engage in bridging to generate a dinuclear system having octahedral Cr(III) centers. The complex was characterized both in solution and in the solid state.
引用
收藏
页码：5116 / 5119
页数：4
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