Synthesis and structure of a five-coordinate organochromium(III) thiolate complex from a chromium(II) alkyl precursor

被引：28
作者：
Fryzuk, MD
Leznoff, DB
Rettig, SJ
机构：
[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 23期
关键词：
D O I：
10.1021/om970574l
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the Cr(II) methyl complex, CrMe[N(SiMe2CH2PPh2)(2)], with diphenyl disulfide (PhSSPh) leads to the formation of the five-coordinate, paramagnetic complex CrMe(SPh)[N(SiMe2CH2PPh2)(2)] by an overall one-electron oxidation. The complex is unusual in that the phenyl thiolate moiety is terminal and does not engage in bridging to generate a dinuclear system having octahedral Cr(III) centers. The complex was characterized both in solution and in the solid state.
引用
收藏
页码：5116 / 5119
页数：4
相关论文
共 50 条
[1]   PHOTOCHEMICAL PREPARATION OF A NEW COMPLEX CONTAINING A MONODENTATE DITHIOCARBAMATE LIGAND - TRICARBONYL(ETA-5-CYCLOPENTADIENYL)(ETA-1-DIMETHYL-CARBAMODITHIOATO)TUNGSTEN(II) [J].
ABRAHAMSON, HB ;
FREEMAN, ML .
ORGANOMETALLICS, 1983, 2 (05) :679-681
[2]   COORDINATION BEHAVIOR OF POTENTIALLY TRIDENTATE DIPHOSPHINOAMIDO LIGANDS - SYNTHESIS AND CRYSTAL-STRUCTURES OF THE COMPLEXES [CRCL(N(CH2CH2PME2)2)2], [CR2CL3(N(CH2CH2PME2)2)(CH2P(ME)CH2CH2NCH2CH2-PME2)] AND [CR2CL4(N(CH2CH2PPR(I)2)2)2] [J].
ALSOUDANI, ARH ;
BATSANOV, AS ;
EDWARDS, PG ;
HOWARD, JAK .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (07) :987-995
[3]  
[Anonymous], INT TABLES XRAY CRYS
[4]   MONONUCLEAR COMPLEXES OF CR(II) AND FE(II) WITH TERMINAL SH-GROUPS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF TRANS-M(SH)2(DMPE)2 (M = CR, FE - DMPE = 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE) [J].
ARIF, AM ;
HEFNER, JG ;
JONES, RA ;
KOSCHMIEDER, SU .
JOURNAL OF COORDINATION CHEMISTRY, 1991, 23 (1-4) :13-19
[5]   PREPARATION AND AQUATION KINETICS OF PENTAAQUO(4-THIOANILINIUM-S)CHROMIUM(III)ION - CATALYSIS OF CHROMIUM-SULFUR BOND BREAKING BY OXYGEN AND OTHER OXIDANTS [J].
ASHER, LE ;
DEUTSCH, E .
INORGANIC CHEMISTRY, 1972, 11 (12) :2927-&
[6]   PREPARATION AND AQUATION KINETICS OF PENTAAQUO(2-MERCAPTOETHYLAMMONIUM-S)CHROMIUM(III) ION - ORIGIN OF K0 TERM IN RATE LAWS OF FORM -D(LN [(H2O)5CRX]N+)/DT=K3+K1(H+) [J].
ASHER, LE ;
DEUTSCH, E .
INORGANIC CHEMISTRY, 1973, 12 (08) :1774-1778
[7]   Activation of organic disulfides by a paramagnetic heterobimetallic tantalum/cobalt complex and a comparison of their reactions with cobaltocene. Evidence for a dependence of mechanism on the electronic properties of the disulfide [J].
Aubart, MA ;
Bergman, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (07) :1793-1794
[8]   STRUCTURE OF A 3-CO-ORDINATE IRON(2) COMPOUND [J].
BRADLEY, DC ;
HURSTHOUSE, MB ;
RODESILER, PF .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (01) :14-+
[9]  
BRADLEY DC, 1971, J CHEM SOC CHEM COMM, P411
[10]   PREPARATION AND REACTIVITY OF TRICARBONYL(ETA-5-CYCLOPENTADIENYL)(ORGANOTHIOLATO)TUNGSTEN COMPLEXES WITH POTENTIALLY CHELATING THIOLATE LIGANDS [J].
BRANDENBURG, KL ;
HEEG, MJ ;
ABRAHAMSON, HB .
INORGANIC CHEMISTRY, 1987, 26 (07) :1064-1069
12345