A novel triphenylamine-based dye sensitizer supported on titania nanoparticles and the effect of titania fabrication on its optical properties

被引:2
作者
Moretti, Elisa [1 ]
Aversa, Manuela [1 ]
Scrivanti, Alberto [1 ]
Storaro, Loretta [1 ]
Talon, Aldo [1 ]
Marin, Riccardo [1 ]
Antonio Cecilia, Juan [3 ]
Rodriguez-Castellon, Enrique [3 ]
Polizzi, Stefano [1 ,2 ]
机构
[1] Univ Ca Foscari Venezia, Dept Mol Sci & Nanosyst, I-30172 Venice, Italy
[2] Univ Ca Foscari Venezia, Electron Microscopy Ctr Giovanni Stevanato, I-30172 Venice, Italy
[3] Univ Malaga, Fac Sci, Dept Inorgan Chem Crystallog & Mineral, E-29071 Malaga, Spain
来源
CHEMICAL PAPERS | 2016年 / 70卷 / 02期
关键词
triarylamine dye sensitizer; titania; anatase; hybrid materials; SOLAR-CELLS; CLICK CHEMISTRY; TIO2; PHASE; CHROMOPHORES; PERFORMANCE; DESIGN; MCM-41; ACID;
D O I
10.1515/chempap-2015-0192
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new synthesised triphenylamine-based dye having a branched structure with one OH-ending branch able to interact with the surface hydroxyl moieties of mesoporous TiO2 is reported. Optical properties of the dye-titania hybrid material are presented and the higher efficiency of the dye on pure anatase TiO2 compared to the commercial Degussa P25, which contains a rutile phase component, is confirmed. The optical and chemical properties of the dye make it a promising candidate as a metal-free dye for DSSCs or as a host for a variety of transition or main group metal ions for different applications. (C) 2015 Institute of Chemistry, Slovak Academy of Sciences
引用
收藏
页码:218 / 230
页数:13
相关论文
共 55 条
  • [1] Synthesis, crystal structure, solution behavior and catalytic activity of a palladium(II)-allyl complex containing a 2-pyridyl-1,2,3-triazole bidentate ligand
    Amadio, E.
    Bertoldini, M.
    Scrivanti, A.
    Chessa, G.
    Beghetto, V.
    Matteoli, U.
    Bertani, R.
    Dolmella, A.
    [J]. INORGANICA CHIMICA ACTA, 2011, 370 (01) : 388 - 393
  • [2] Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces
    Ardo, Shane
    Meyer, Gerald J.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 115 - 164
  • [3] Armarego W.L. F., 1996, PURIFICATION LAB CHE, V4th
  • [4] Barbe CJ, 1997, J AM CERAM SOC, V80, P3157, DOI 10.1111/j.1151-2916.1997.tb03245.x
  • [5] Prediction of TiO2 nanoparticle phase and shape transitions controlled by surface chemistry
    Barnard, AS
    Curtiss, LA
    [J]. NANO LETTERS, 2005, 5 (07) : 1261 - 1266
  • [6] Synthesis and NMR Analysis of 1,4-Disubstituted 1,2,3-Triazoles Tethered to Pyridine, Pyrimidine, and Pyrazine Rings
    Bolje, Aljosa
    Urankar, Damijana
    Kosmrlj, Janez
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (36) : 8167 - 8181
  • [7] Apparent Copper(II)-Accelerated Azide-Alkyne Cycloaddition
    Brotherton, Wendy S.
    Michaels, Heather A.
    Simmons, J. Tyler
    Clark, Ronald J.
    Dalal, Naresh S.
    Zhu, Lei
    [J]. ORGANIC LETTERS, 2009, 11 (21) : 4954 - 4957
  • [8] Rigid triarylamine-based efficient DSSC sensitizers with high molar extinction coefficients
    Cai, Shengyun
    Hu, Xiaohao
    Zhang, Zhiyun
    Su, Jianhua
    Li, Xin
    Islam, Ashraful
    Han, Liyuan
    Tian, He
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (15) : 4763 - 4772
  • [9] Mesoporous Anatase TiO2 Beads with High Surface Areas and Controllable Pore Sizes: A Superior Candidate for High-Performance Dye-Sensitized Solar Cells
    Chen, Dehong
    Huang, Fuzhi
    Cheng, Yi-Bing
    Caruso, Rachel A.
    [J]. ADVANCED MATERIALS, 2009, 21 (21) : 2206 - +
  • [10] Photogenerated Defects in Shape-Controlled TiO2 Anatase Nanocrystals: A Probe To Evaluate the Role of Crystal Facets in Photocatalytic Processes
    D'Arienzo, Massimiliano
    Carbajo, Jaime
    Bahamonde, Ana
    Crippa, Maurizio
    Polizzi, Stefano
    Scotti, Roberto
    Wahba, Laura
    Morazzoni, Franca
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (44) : 17652 - 17661