Photooxidative Cleavage of Aromatic Alkenes into Aldehydes Using Catalytic Iodine and Molecular Oxygen under Visible Light Irradiation

被引：34

作者：

Fujiya, Akitoshi ^{[1
]}

Kariya, Atsumasa ^{[1
]}

Nobuta, Tomoya ^{[1
]}

Tada, Nirohiro ^{[1
]}

Miura, Tsuyoshi ^{[2
]}

Itoh, Akichika ^{[1
]}

机构：

[1] Gifu Pharmaceut Univ, Gifu 5011196, Japan

[2] Tokyo Univ Pharm & Life Sci, Hachioji, Tokyo 1920392, Japan

来源：

SYNLETT | 2014年 / 25卷 / 06期

基金：

日本学术振兴会;

关键词：

alkenes; aerobic; photooxidation; iodine; aldehydes; CARBON BOND-CLEAVAGE; OXIDATIVE CLEAVAGE; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; PHENACYL IODIDES; ALLYLIC-ALCOHOLS; BENZYL-ALCOHOLS; CALCIUM IODIDE; STYRENES; EXPLOSION;

D O I：

10.1055/s-0033-1340735

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a method for the photooxidative cleavage of aromatic alkenes to give aldehydes using molecular oxygen as the terminal oxidant, visible light, a catalytic amount of iodine and trifluoroacetic acid.

引用

收藏

页码：884 / 888

页数：5

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