Human hair-derived carbon flakes for electrochemical supercapacitors

被引:915
作者
Qian, Wenjing [1 ]
Sun, Fengxia [2 ]
Xu, Yanhui [2 ]
Qiu, Lihua [1 ]
Liu, Changhai [3 ]
Wang, Suidong [3 ]
Yan, Feng [1 ]
机构
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
[2] Soochow Univ, Inst Chem Power Sources, Suzhou 215006, Peoples R China
[3] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
关键词
HIGH-PERFORMANCE SUPERCAPACITOR; CO-DOPED CARBONS; ELECTRODE MATERIALS; ENERGY-STORAGE; GRAPHENE; FILMS; CAPACITORS; NETWORK; FIBERS; PAPER;
D O I
10.1039/c3ee43111h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heteroatom doped porous carbon flakes were prepared via carbonization of Chinese human hair fibers and employed for high-performance supercapacitor electrode materials. The morphology and chemical composition of the resultant carbon materials were characterized by electron microscopy (EM), energydispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) measurements. Human hair carbonized at 800 degrees C exhibited high charge storage capacity with a specific capacitance of 340 F g(-1) in 6 M KOH at a current density of 1 A g(-1). and good stability over 20 000 cycles. The specific capacitance of 126 F g(-1) is also verified in a 1 M LiPF6 ethylene carbonate/diethyl carbonate (EC/DEC) organic electrolyte at a current density of 1 A g(-1). The high supercapacitor performance could be due to the micro/mesoporosity combined with high effective surface area and heteroatom doping effects, combining double layer and Faradaic contributions.
引用
收藏
页码:379 / 386
页数:8
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