Toward Practical Application Of H2 Generation From Ammonia Decomposition Guided by Rational Catalyst Design

被引：103

作者：

Garcia-Bordeje, Enrique ^{[1
]}

Armenise, Sabino ^{[1
]}

Roldan, Laura ^{[1
]}

机构：

[1] Inst Carboquim ICB CSIC, Zaragoza 50018, Spain

来源：

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2014年 / 56卷 / 02期

关键词：

Ammonia decomposition; H-2; generation; Structured reactor; Supported metal catalyst; COX-FREE HYDROGEN; DENSITY-FUNCTIONAL THEORY; CELL POWER-SUPPLIES; NH3; DECOMPOSITION; STRUCTURE SENSITIVITY; RU CATALYSTS; BIMETALLIC CATALYSTS; RUTHENIUM CATALYSTS; SURFACE SEGREGATION; CARBON NANOTUBES;

D O I：

10.1080/01614940.2014.903637

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This perspective article focuses on the recent advances in the rational design of catalyst for NH3 decomposition at different length scales, from catalyst nanoparticles to reactor design. For an overall optimum performance, all scales should be optimized in a concerted manner. The study of the mechanism of reaction has given guidelines for the catalyst design. As far as reactor design is concerned, a structured reactor is beneficial for this reaction because it minimizes the inhibiting effect of produced H-2, besides other inherent advantages. This holistic optimization of catalysts is expected to pave the way for application of NH3 as H-2 storage media.

引用

收藏

页码：220 / 237

页数：18

相关论文

共 69 条

[11] Microreactor modeling for hydrogen production from ammonia decomposition on ruthenium [J].

Deshmukh, SR ;

Mhadeshwar, AB ;

Vlachos, DG .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (12) :2986-2999

[12] Tamaru's model for ammonia decomposition over titanium oxynitride [J].

Djéga-Mariadassou, G ;

Shin, CH ;

Bugli, G .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 141 (1-3) :263-267

[13] MCM-41 supported Co-Mo bimetallic catalysts for enhanced hydrogen production by ammonia decomposition [J].

Duan, Xuezhi ;

Qian, Gang ;

Zhou, Xinggui ;

Chen, De ;

Yuan, Weikang .

CHEMICAL ENGINEERING JOURNAL, 2012, 207 :103-108

[14] Ammonia decomposition on Fe(110), Co(111) and Ni(111) surfaces: A density functional theory study [J].

Duan, Xuezhi ;

Ji, Jian ;

Qian, Gang ;

Fan, Chen ;

Zhu, Yian ;

Zhou, Xinggui ;

Chen, De ;

Yuan, Weikang .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 357 :81-86

[15] First-principles calculations of ammonia decomposition on Ni(110) surface [J].

Duan, Xuezhi ;

Qian, Gang ;

Fan, Chen ;

Zhu, Yian ;

Zhou, Xinggui ;

Chen, De ;

Yuan, Weikang .

SURFACE SCIENCE, 2012, 606 (3-4) :549-553

[16] Carbon Nanofiber-Supported Ru Catalysts for Hydrogen Evolution by Ammonia Decomposition [J].

Duan Xuezhi ;

Zhou Jinghong ;

Qian Gang ;

Li Ping ;

Zhou Xinggui ;

Chen De .

CHINESE JOURNAL OF CATALYSIS, 2010, 31 (08) :979-986

[17] Pressure drop measurements and hydrodynamic model description of SiC foam composites decorated with SiC nanofiber [J].

Edouard, David ;

Ivanova, Svetlana ;

Lacroix, Maxime ;

Vanhaecke, Estelle ;

Pham, Charlotte ;

Pham-Huu, Cuong .

CATALYSIS TODAY, 2009, 141 (3-4) :403-408

[18] AMMONIA DECOMPOSITION ON (1 1 10) AND (0 0 1) SURFACES OF RUTHENIUM [J].

EGAWA, C ;

NISHIDA, T ;

NAITO, S ;

TAMARU, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :1595-1604

[19]

ERTL G, 1982, SURF SCI, V119, pL314, DOI 10.1016/0039-6028(82)90173-X

[20] Porous anodic alumina microreactors for production of hydrogen from ammonia [J].

Ganley, JC ;

Seebauer, EG ;

Masel, RI .

AICHE JOURNAL, 2004, 50 (04) :829-834

← 1 2 3 4 5 6 7 →