Surface States in Ternary CdSSe Quantum Dot Solar Cells

被引：5

作者：

Chen, Zhenhua ^{[1
]}

Li, Hui ^{[2
]}

Zhang, Xiangzhi ^{[1
]}

Zhang, Lijuan ^{[1
]}

Yu, Huaina ^{[1
]}

Li, Wenqin ^{[1
]}

Xu, Zijian ^{[1
]}

Wang, Yong ^{[1
]}

Tai, Renzhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201800, Peoples R China

[2] Donghua Univ, Dept Appl Phys, Shanghai 201620, Peoples R China

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2017年 / 17卷 / 02期

基金：

美国国家科学基金会;

关键词：

Surface States; Ternary; Quantum Dot; Solar Cell; Synchrotron; X-RAY-ABSORPTION; TIO2; FILMS; DYE; SIZE; RECOMBINATION; PERFORMANCE; EFFICIENCY;

D O I：

10.1166/jnn.2017.12629

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ternary CdSSe quantum dot-sensitized solar cells (QDSCs) have demonstrated advantages such as wide absorption ranges and tunable band structures. However, the oxygen additives absorbed on such multicomponent quantum dot (QD) surfaces induce band bending at the TiO2/CdSSe interface and prevent charge transport in QDSCs, as determined via X-ray photoelectron spectroscopy (XPS) and synchrotron-based X-ray Absorption Near-Edge Structure (XANES) analysis. Annealing of TiO2/CdSSe QDs photoanodes was conducted at different temperatures under Ar atmospheres to eliminate oxygen additives and interfacial band bending. The short-circuit current (Jsc) of the annealed ternary CdSSe QDSCs is obviously improved, whereas the TiCl4 treatment and MgO coating of the TiO2 nanocrystals are assisted by the annealing to compensate for the loss of opencircuit voltage (V-oc) and fill factor (FF). Ternary CdSSe QDSCs with efficiencies of 4.72% have been achieved using the optimized

引用

页码：1373 / 1380

页数：8

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