New Progress in Monomeric Phthalocyanine Chemistry: Synthesis, Crystal Structures and Properties

被引：7

作者：

Ni, Zhonghai ^{[1
]}

Li, Renjie ^{[1
]}

Jiang, Jianzhuang ^{[1
]}

机构：

[1] Shandong Univ, Dept Chem, Jinan 250100, Peoples R China

来源：

CONTROLLED ASSEMBLY AND MODIFICATION OF INORGANIC SYSTEMS | 2009年 / 133卷

基金：

中国国家自然科学基金;

关键词：

Crystal structure; Modification; Phthalocyanine; Property; Synthesis; X-RAY STRUCTURES; METAL-FREE PHTHALOCYANINE; MAGNESIUM PHTHALOCYANINE; SPECTROSCOPIC PROPERTIES; MAGNETIC-PROPERTIES; THERMAL-STABILITY; AXIAL LIGAND; COMPLEX; ELECTROCHEMISTRY; NAPHTHALOCYANINE;

D O I：

10.1007/430_2008_13

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this chapter, recent progress in the synthesis, crystal structures and physical properties of monomeric phthalocyanines (Pcs) is summarized and analysed. The strategies for synthesis and modification of Pcs include axial coordination of central metal ions, peripheral substitution of Pc rings and the ionization of Pcs. The crystal structures of various typical Pcs, especially the effects of different synthetic and modification strategies on the supramolecular assemblies of Pcs via pi-pi interactions between Pc rings, are discussed in detail. Finally, the UV-vis spectroscopic, conducting, magnetic and catalytic properties of some Pcs with crystal structures are presented briefly, and the correlations between various properties and the molecular structure discussed.

引用

页码：121 / 160

页数：40

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