Preparation of non-cross-linked polystyrene-supported quaternary ammonium salts and use as phase transfer catalysts under microwave

被引：17
作者：
Chen, ZX [1 ]
Xu, GY [1 ]
Yang, GC [1 ]
Wang, W [1 ]
机构：
[1] Hubei Univ, Fac Chem & mat Sci, Wuhan 430062, Peoples R China
来源：
REACTIVE & FUNCTIONAL POLYMERS | 2004年 / 61卷 / 01期
基金：
中国国家自然科学基金;
关键词：
non-cross-linked chloromethyl polystyrene; support; quaternary ammonium salts; phase transfer catalysis; microwave irradiation;
D O I：
10.1016/j.reactfunctpolym.2004.05.005
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Non-cross-linked chloromethyl polystyrene (NCPS) with high loading and excellent solubility has been effectively and facilely prepared using radical copolymerization of styrene and p-chloromethyl styrene under microwave irradiation. The NCPS supported quaternary ammonium salts have also been prepared by two different methods: chemical modification reactions on NCPS and one-pot reaction of St, CMS and TBA. The catalysts coupled the advantages of conventional solution phase catalysts and insoluble polymer-supported catalysts, catalyzed some nucleophilic substitution reactions under phase transfer catalysis condition effectively under microwave irradiation. (C) 2004 Elsevier B.V. All rights reserved.
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页码：139 / 146
页数：8
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