A highly selective dual channel hypochlorite probe based on fluorescein and 1,10-phenanthroline

被引：21
作者：
Algi, Melek Pamuk [1 ,2 ]
机构：
[1] Aksaray Univ, Hlth Serv Vocat Sch, TR-68100 Aksaray, Turkey
[2] Aksaray Univ, ASUBTAM BioNanoTech Lab, TR-68100 Aksaray, Turkey
来源：
TETRAHEDRON | 2016年 / 72卷 / 12期
关键词：
Fluorescence; Probe; Hypochlorite; 1,10-Phenanthroline; Fluorescein; Chromogenic; ACID; CHEMODOSIMETER; SENSORS;
D O I：
10.1016/j.tet.2016.02.004
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this study, a highly selective dual channel (UV-vis and fluorescence) responsive hypochlorite probe based on fluorescein and 1,10-phenanthroline is described. It is found that this compound can be used as both a fluorogenic and chromogenic probe for the detection of the hypochlorite ion in aqueous solution. NMR and mass spectral analysis show that the probe reacts with the hypochlorite ion, which triggers both a remarkable enhancement of the emission intensity (turn on), and a color change from a colorless state to yellow. More importantly, the probe displays extremely high selectivity to hypochlorite among other common ROS and many ions in aqueous solution. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1558 / 1565
页数：8
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  • [1] An electroactive polymeric material and its voltammetric response towards alkali metal cations in neat water
    Algi, Fatih
    Cihaner, Atilla
    [J]. TETRAHEDRON LETTERS, 2008, 49 (21) : 3530 - 3533
  • [2] Triple channel responsive Cu2+ probe
    Algi, Melek Pamuk
    Oztas, Zahide
    Algi, Fatih
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (82) : 10219 - 10221
  • [3] A Diverse-Stimuli Responsive Chemiluminescent Probe with Luminol Scaffold and Its Electropolymerization
    Asil, Demet
    Cihaner, Atilla
    Algi, Fatih
    Onal, Ahmet M.
    [J]. ELECTROANALYSIS, 2010, 22 (19) : 2254 - 2260
  • [4] Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system
    Atilgan, Nurdan
    Algi, Fatih
    Onal, Ahmet M.
    Cihaner, Atilla
    [J]. TETRAHEDRON, 2009, 65 (29-30) : 5776 - 5781
  • [5] Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer
    Atilgan, Serdar
    Ozdemir, Tugba
    Akkaya, Engin U.
    [J]. ORGANIC LETTERS, 2010, 12 (21) : 4792 - 4795
  • [6] Luminescent sensors and switches in the early 21st century
    Callan, JF
    de Silva, AP
    Magri, DC
    [J]. TETRAHEDRON, 2005, 61 (36) : 8551 - 8588
  • [7] A "turn-on" fluorescent probe for hypochlorous acid: convenient synthesis, good sensing performance, and a new design strategy by the removal of C=N isomerization
    Cheng, Xiaohong
    Jia, Huizhen
    Long, Teng
    Feng, Jun
    Qin, Jingui
    Li, Zhen
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (43) : 11978 - 11980
  • [8] Ion sensing coupled to resonance energy transfer: A highly selective and sensitive ratiometric fluorescent chemosensor for Ag(I) by a modular approach
    Coskun, A
    Akkaya, EU
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (30) : 10464 - 10465
  • [9] Combining luminescence, coordination and electron transfer for signalling purposes
    de Silva, AP
    Fox, DB
    Huxley, AJM
    Moody, TS
    [J]. COORDINATION CHEMISTRY REVIEWS, 2000, 205 : 41 - 57
  • [10] Signaling recognition events with fluorescent sensors and switches
    de Silva, AP
    Gunaratne, HQN
    Gunnlaugsson, T
    Huxley, AJM
    McCoy, CP
    Rademacher, JT
    Rice, TE
    [J]. CHEMICAL REVIEWS, 1997, 97 (05) : 1515 - 1566
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