High electrochemical performance of rGO anchored CuS nanospheres for supercapacitor applications

被引:91
作者
El-Hout, Soliman I. [1 ]
Mohamed, Saad G. [2 ]
Gaber, Amira [1 ]
Attia, Sayed Y. [2 ]
Shawky, Ahmed [1 ]
El-Sheikh, Said M. [1 ]
机构
[1] Cent Met R&D Inst CMRDI, Nanomat & Nanotechnol Dept, Adv Mat Div, POB 87, Cairo 11421, Egypt
[2] Tabbin Inst Met Studies TIMS, Min & Met Engn Dept, Helwan 109, Cairo 11421, Egypt
来源
JOURNAL OF ENERGY STORAGE | 2021年 / 34卷 / 34期
关键词
CuS; Nanocomposite; Graphene; Hybrid supercapacitors; Energy density; ONE-POT SYNTHESIS; GRAPHENE OXIDE NANOCOMPOSITES; EFFICIENT ELECTRODE MATERIAL; FACILE SYNTHESIS; PHOTOCATALYTIC REDUCTION; HYDROTHERMAL SYNTHESIS; STORAGE PROPERTIES; HIERARCHICAL CUS; NANOWIRE ARRAYS; NANOPARTICLES;
D O I
10.1016/j.est.2020.102001
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Hexagonal CuS nanoparticles supported on rGO sheets were magnificently produced through a simple in-situ wet reduction process for high-performance supercapacitors. The as-obtained composites were analyzed using numerous techniques. The results revealed that 7% rGO anchored CuS nanospheres (NS) was the lowest sp(2) domain crystallite size, maximum surface area (34.4 m(2).g(-1)), and most expansive pore volume (0.0595 cm(3).g(-1)). Furthermore, HR-TEM showed regular and uniform dissemination of CuS NS over rGO sheets. The CuS/7%rGO exhibits the highest specific capacity of 235 C g(-1) at 1 A g(-1) and can maintain 95% of its particular original capacity after 2000 cycles at a great current density of 10 A g(-1). Besides, the CuS/7%rGO/AC hybrid SC device displayed the highest energy density of 43Wh kg(-1) at a power density of 1426W kg(-1) and a current density of 1 A g(-1).
引用
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页数:9
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