2D Metal Chalcogenides Incorporated into Carbon and their Assembly for Energy Storage Applications

被引:53
作者
Deng, Zongnan [1 ,2 ]
Jiang, Hao [1 ,2 ]
Li, Chunzhong [1 ,2 ]
机构
[1] East China Univ Sci & Technol, Key Lab Ultrafine Mat, Minist Educ, POB 258,130 Meilong Rd, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Sch Mat Sci & Engn, POB 258,130 Meilong Rd, Shanghai 200237, Peoples R China
基金
中国国家自然科学基金;
关键词
2D materials; carbon; energy storage; incorporated nanostructures; metal chalcogenides; LITHIUM-ION BATTERIES; MOS2; NANOSHEETS; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; GRAPHENE FOAM; NANOFIBERS; NANOTUBES; SUPERCAPACITORS; NANOSTRUCTURES; NETWORK;
D O I
10.1002/smll.201800148
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D metal chalcogenides have become a popular focus in the energy storage field because of their unique properties caused by their single-atom thicknesses. However, their high surface energy and van der Waals attraction easily cause serious stacking and restacking, leading to the generation of more inaccessible active sites with rapid capacity fading. The hybridization of 2D metal chalcogenides with highly conductive materials, particularly, incorporating ultrasmall and few-layered metal chalcogenides into carbon frameworks, can not only maximize the exposure of active sites but also effectively avoid their stacking and aggregation during the electrochemical reaction process. Therefore, a satisfactory specific capacity will be achieved with a long cycle life. In this Concept, the representative progress on such intriguing nanohybrids and their applications in energy storage devices are mainly summarized. Finally, an outlook of the future development and challenges of such nanohybrids for achieving an excellent energy storage capability is also provided.
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页数:9
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