Preparation of alkyl nitrates, nitrites, and thiocyanates from alcohols utilizing trichloroisocyanuric acid with triphenylphosphine

被引：16

作者：

Hiegel, GA ^{[1
]}

Nguyen, J ^{[1
]}

Zhou, Y ^{[1
]}

机构：

[1] Calif State Univ Fullerton, Dept Chem & Biochem, Fullerton, CA 92834 USA

来源：

SYNTHETIC COMMUNICATIONS | 2004年 / 34卷 / 14期

关键词：

alcohols; alkyl nitrates; alkyl nitrites; alkyl thiocyanates; substitution; preparation; synthesis; trichloroisocyanuric acid; triphenylphosphine;

D O I：

10.1081/SCC-200025580

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alcohols in acetonitrile are converted into alkyl nitrates, nitrites, or thiocyanates by the action of triphenylphosphine and trichloroisocyan. uric acid along with silver nitrate, silver nitrite, or sodium thiocyanate, respectively.

引用

页码：2507 / 2511

页数：5

共 5 条

[1]

CONLEY RT, 1966, INFRARED SPECTROSCOP, P117

[2] Conversion of alcohols into alkyl chlorides using trichloroisocyanuric acid with triphenylphosphine [J].

Hiegel, GA ;

Rubino, M .

SYNTHETIC COMMUNICATIONS, 2002, 32 (17) :2691-2694

[3] Chlorine substitution reactions using trichloroisocyanuric acid with triphenylphosphine [J].

Hiegel, GA ;

Ramírez, J ;

Barr, RK .

SYNTHETIC COMMUNICATIONS, 1999, 29 (08) :1415-1419

[4]

Noyes W. A., 1943, ORG SYNTH, V2, P108

[5] ORGANIC NITRATES AS SYNTHETIC INTERMEDIATES - PREPARATIONS OF NITRATES AND SOME REPRESENTATIVE REACTIONS [J].

PATTISON, FLM ;

BROWN, GM .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1956, 34 (07) :879-884

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