Design and synthesis of a 4-(2′-pyridyl)-1,2,3,5-dithiadiazolyl cobalt complex

被引：59

作者：

Hearns, NGR

Preuss, KE ^{[1
]}

Richardson, JF

Bin-Salamon, S

机构：

[1] Univ Guelph, Dept Chem, Guelph, ON N1G 2W1, Canada

[2] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

[3] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 32期

关键词：

D O I：

10.1021/ja046304t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 4-(2′-pyridyl)-1,2,3,5-dithiadiazolyl neutral radical 1 has been prepared for use as a spin-bearing bidentate ligand. The coordination of this ligand to bis(hexafluoroacetylacetonato)cobalt affords a thermally stable complex 2. Magnetic susceptibility measurements of the crystalline complex indicate ferromagnetic coupling between the ligand-centered spin and the unpaired electrons of the high-spin Co(II). Copyright © 2004 American Chemical Society.

引用

页码：9942 / 9943

页数：2

共 27 条

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