Study of catalytic decomposition of formaldehyde on Pt/TiO2 alumite catalyst at ambient temperature

被引:91
作者
Wang, Lifeng [1 ]
Sakurai, Makoto [1 ]
Kameyama, Hideo [1 ]
机构
[1] Tokyo Univ Agr & Technol, Kameyama & Sakurai Lab, Dept Chem Engn, Fac Engn, Koganei, Tokyo 1848588, Japan
关键词
Formaldehyde; Pt/TiO2/Al2O3; Structured catalyst; Anodic alumite film; TPD; TPR; ROOM-TEMPERATURE; PLATINUM CATALYSTS; ANODIZED ALUMINUM; OXIDIZING ATMOSPHERE; SUPPORTING METHOD; OXIDATION; COMBUSTION; TIO2; VOCS; CO;
D O I
10.1016/j.jhazmat.2008.12.129
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Formaldehyde (HCHO) emitted from buildings. furnishing materials and consumer products is one of the most dominant volatile organic compounds (VOCs) in an indoor environment. In this work, a Pt/TiO2/Al2O3 catalyst was prepared on an anodic alumite plate and was employed in the catalytic decomposition of formaldehyde at ambient temperature. Firstly, TiO2 was deposited on the anodic alumite plate with electro-deposition technology. Then, platinum was supported on the anodic alumite plate with wet impregnation method. The developed catalyst exhibits good activity towards the decomposition of HCHO at ambient temperature. TPR (temperature programmed reduction) and TPD (temperature programmed desorption) analysis results indicate that oxygen adsorbed on the Pt/TiO2/Al2O3 catalyst can be activated and generated to O:Pt-surface species quickly at ambient temperature. Hence, the developed catalyst experiences the high activity towards the catalytic decomposition of formaldehyde at ambient temperature. Moreover, in accordance with the process requirements, the developed catalyst can be formed into various shapes such as a mesh, plate, fin, serrate etc., because aluminum can be formed into any shapes. The serrate type catalyst was prepared in this work and it also exhibits fine activity towards the decomposition of HCHO. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:399 / 405
页数:7
相关论文
共 26 条
[1]   Effects of reduction temperature and metal-support interactions on the catalytic activity Pt/γ-Al2O3 and Pt/TiO2 for the oxidation of CO in the presence and absence of H2 [J].
Alexeev, OS ;
Chin, SY ;
Engelhard, MH ;
Ortiz-Soto, L ;
Amiridis, MD .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (49) :23430-23443
[2]   Formaldehyde/methanol combustion on alumina-supported manganese-palladium oxide catalyst [J].
Alvarez-Galván, MC ;
Pawelec, B ;
O'Shea, VAD ;
Fierro, JLG ;
Arias, PL .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 51 (02) :83-91
[3]   Indoor air purification by photocatalyst TiO2 immobilized on an activated carbon filter installed in an air cleaner [J].
Ao, CH ;
Lee, SC .
CHEMICAL ENGINEERING SCIENCE, 2005, 60 (01) :103-109
[4]   Theoretical assessment of the catalytic (Pt/TiO2) oxidation of formaldehyde at ambient temperature [J].
Dewil, R ;
Everaert, K ;
Baeyens, J .
CATALYSIS COMMUNICATIONS, 2005, 6 (12) :793-795
[5]   Honeycomb supports with high thermal conductivity for gas/solid chemical processes [J].
Groppi, G ;
Tronconi, E .
CATALYSIS TODAY, 2005, 105 (3-4) :297-304
[6]   Design of novel monolith catalyst supports for gas/solid reactions with heat exchange [J].
Groppi, G ;
Tronconi, E .
CHEMICAL ENGINEERING SCIENCE, 2000, 55 (12) :2161-2171
[7]   FTIR and mass spectrometric studies on the interaction of formaldehyde with TiO2 supported Pt and Au catalysts [J].
Kecskés, T ;
Raskó, J ;
Kiss, J .
APPLIED CATALYSIS A-GENERAL, 2004, 273 (1-2) :55-62
[8]   Optimization of structured catalyst carriers for VOC combustion [J].
Kolodziej, A ;
Lojewska, J .
CATALYSIS TODAY, 2005, 105 (3-4) :378-384
[9]   Catalytic combustion of formaldehyde on gold/iron-oxide catalysts [J].
Li, Changyan ;
Shen, Yuenian ;
Jia, Melling ;
Sheng, Shishan ;
Adebajo, Moses O. ;
Zhu, Huaiyong .
CATALYSIS COMMUNICATIONS, 2008, 9 (03) :355-361
[10]   Effect of photocatalytic activity of CO oxidation on Pt/TiO2 by strong interaction between Pt and TiO2 under oxidizing atmosphere [J].
Li, Qiuye ;
Wang, Ke ;
Zhang, Shunli ;
Zhang, Min ;
Yang, Hanjun ;
Jin, Zhensheng .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 258 (1-2) :83-88