Annealing temperature effect on field emission of silicon emitter arrays with sol-gel (Ba0.65Sr0.35)TiO3 coatings

被引:4
作者
Lu, H.
Chen, F.
Zhu, W. G.
Pan, J. S.
Tan, O. K.
机构
[1] Nanyang Technol Univ, Ctr Microelect, Sch Elect & Elect Engn, Singapore 639798, Singapore
[2] Inst Mat Res & Engn, Singapore 117602, Singapore
关键词
BST thin film; electron emission; sol-gel;
D O I
10.1080/00150190600695941
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ba0.65Sr0.35TiO3 (BST) thin films have been fabricated on silicon field emitter arrays (FEAs) using sol-gel coating for electron emission applications. The BSTcoatings exhibit the perovskite structure when annealed between 650 and 700 degrees C, and an interfacial reaction occurs when annealed above 750 degrees C The threshold electric field is lowered from 36 V/mu m for bare silicon tips to 19 V/mu m for BST-coated silicon tips. The oxygen vacancy concentration increases for BST thin films annealed from 600 to 750 degrees C, and decreases above 750 degrees C, leading to the Fermi energy shift. The electron emission behavior is correlated to both the microstructure and electronic structure of the BST thin films.
引用
收藏
页码:253 / 261
页数:9
相关论文
共 19 条
[1]   Enhanced field emission of silicon tips coated with sol-gel-derived (Ba0.65Sr0.35)TiO3 thin film [J].
Chen, XF ;
Lu, H ;
Zhu, WG ;
Tan, OK .
SURFACE & COATINGS TECHNOLOGY, 2005, 198 (1-3) :266-269
[2]   Effect of donor and acceptor dopants on Schottky barrier heights and vacancy concentrations in barium strontium titanate [J].
Dawber, M ;
Scott, JF ;
Hartmann, AJ .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1633-1636
[3]   Effect of gases on the field emission properties of ultrananocrystalline diamond-coated silicon field emitter arrays [J].
Hajra, M ;
Hunt, CE ;
Ding, M ;
Auciello, O ;
Carlisle, J ;
Gruen, DM .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (06) :4079-4083
[4]   An investigation on the utilization of perovskite-type oxides La1-xSrxMO3 (M = Co0.77Bi0.20Pd0.03) as three-way catalysts [J].
He, H ;
Dai, HX ;
Au, CT .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 33 (01) :65-80
[5]   Emission characteristics of TiN-coated silicon field emitter arrays [J].
Kang, SY ;
Lee, JH ;
Song, YH ;
Kim, YT ;
Cho, KI ;
Yoo, HJ .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1998, 16 (02) :871-874
[6]   Effect of annealing temperature on the electron emission characteristics of silicon tips coated with Ba0.67Sr0.33TiO3 thin film [J].
Kang, WP ;
Wisitsora-at, A ;
Davidson, JL ;
Tan, OK ;
Zhu, WG ;
Li, Q ;
Xu, JF .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2003, 21 (01) :453-457
[7]   Electron emission from silicon tips coated with sol-gel (Ba0.67Sr0.33)TiO3 ferroelectric thin film [J].
Kang, WP ;
Wisitsora-at, A ;
Davidson, JL ;
Tan, OK ;
Zhu, WG ;
Li, Q ;
Xu, JF .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2001, 19 (03) :1073-1076
[8]   Effects of post-annealing on the dielectric properties of Au/BaTiO3/Pt thin film capacitors [J].
Lee, EJH ;
Pontes, FM ;
Leite, ER ;
Longo, E ;
Magnani, R ;
Pizani, PS ;
Varela, JA .
MATERIALS LETTERS, 2004, 58 (11) :1715-1721
[9]   CORRELATION BETWEEN FOURIER-TRANSFORM-INFRARED (FTIR) SPECTRA AND TEMPERATURE-DEPENDENCE OF DIELECTRIC-PROPERTIES OF SRTIO3 THIN-FILMS [J].
MATSUI, K ;
TAGA, M ;
KOBAYASHI, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1993, 32 (6A) :L796-L798
[10]   Single-crystal IR spectroscopic investigation on fresnoite, Sr-fresnoite and Ge-fresnoite [J].
Mayerhöfer, TG ;
Dunken, HH .
VIBRATIONAL SPECTROSCOPY, 2001, 25 (02) :185-195