Halogen exchange by reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its mechanistic study

被引：7

作者：

Kuniyasu, Hitoshi ^{[1
]}

Sanagawa, Atsushi ^{[1
]}

Nakajima, Takuya ^{[1
]}

Iwasaki, Takanori ^{[1
]}

Kambe, Nobuaki ^{[1
]}

Bobuatong, Karan ^{[2
,3
]}

Ehara, Masahiro ^{[2
,3
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan

[2] Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

[3] Kyoto Univ, ESICB, Kyoto 6158510, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 769卷

基金：

日本学术振兴会;

关键词：

Ruthenium; Acid halide; Halogen exchange; DFT calculation; Radical mechanism; CYCLOPENTADIENYL-RUTHENIUM COMPLEXES; RADICAL-ADDITION REACTIONS; SIGMA-BOND METATHESIS; OXIDATIVE ADDITION; CRYSTAL-STRUCTURES; ALLYLIC HALIDES; ATOM; CHEMISTRY; KINETICS; ROUTE;

D O I：

10.1016/j.jorganchem.2014.06.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of CpRu(Cl)(PPh3)(2) with MeC(O)X offers a very convenient procedure for the synthesis of CpRu(X)(PPh3)(2). The proposed mechanism involves an intermediate produced by the concerted liberation of PPh3 by the incoming MeC(O)X and the subsequent subtraction of the X atom by the Ru atom to form a radical pair. (c) 2014 Elsevier B.V. All rights reserved.

引用

页码：34 / 37

页数：4

共 49 条

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