A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes

被引：361

作者：

MacNeil, DD

Lu, ZH

Chen, ZH

Dahn, JR ^{[1
]}

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 3J5, Canada

[2] Dalhousie Univ, Dept Phys, Halifax, NS B3H 3J5, Canada

来源：

JOURNAL OF POWER SOURCES | 2002年 / 108卷 / 1-2期

关键词：

DSC; cathodes; lithium-ion;

D O I：

10.1016/S0378-7753(01)01013-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Differential scanning calorimetry (DSC) was used to compare the thermal stability of charged cathodes in 1 M LiPF6 EC/DEC electrolyte. Seven possible cathode materials for lithium-ion batteries (LiCoO2 LiNiO2 LiNi0.8Co0.2O2, LiNi0.7Ti0.05Mn0.05O2, Li[Ni3/8Co1/4Mn3/8]O-2, and LiFePO4 were tested under the same condition Welded stainless steel DSC sample tubes, that ensured no weight loss during analysis, were used for these measurements, making them reliable. A consideration of these DSC results and the known electrochemical properties of the cathodes may assist the selection of the most suitable lithium-ion cathode material for use in a particular application. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：8 / 14

页数：7

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