Compressibility of Ca3Al2Si3O12 perovskite up to 55 GPa

被引:4
作者
Greaux, Steeve [1 ,2 ]
Andrault, Denis [3 ]
Gautron, Laurent [4 ]
Bolfan-Casanova, Nathalie [3 ]
Mezouar, Mohamed [5 ]
机构
[1] Ehime Univ, Geodynam Res Ctr, Matsuyama, Ehime 7908577, Japan
[2] Tokyo Inst Technol, Earth Life Sci Inst, Tokyo 1528550, Japan
[3] Univ Blaise Pascal, Lab Magmas & Volcans, Clermont Ferrand, France
[4] Univ Paris Est, Lab Geomat & Geol Ingn, Marne La Vallee, France
[5] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
Grossular garnet; CaSiO3; perovskite; Aluminum; High pressure; In situ X-ray diffraction; EQUATION-OF-STATE; HIGH-PRESSURE; CASIO3; PEROVSKITE; PHASE-RELATIONS; AB-INITIO; TRANSITION; GARNET; SYSTEM; AL; TRANSFORMATION;
D O I
10.1007/s00269-014-0673-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Compressibility of perovskite-structured Ca3Al2Si3O12 grossular (GrPv) was investigated at high pressure and high temperature by means of angle-dispersive powder X-ray diffraction using a laser-heated diamond anvil cell. We observed the Pbnm orthorhombic distortion for the pure phase above 50 GPa, whereas below this pressure, Al-bearing CaSiO3 perovskite coexists with an excess of corundum. GrPv has a bulk modulus (K (0) = 229 +/- A 5 GPa; fixed to 4) almost similar to that reported for pure CaSiO3 perovskite. Its unit-cell volume extrapolated to ambient conditions (V (0) = 187.1 +/- A 0.4 (3)) is found to be similar to 2.5 % larger than for the Al-free phase. We observe an increasing unit-cell anisotropy with increasing pressure, which could have implications for the shear properties of Ca-bearing perovskite in cold slabs subducted into the Earth's mantle.
引用
收藏
页码:419 / 429
页数:11
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