Mechanically Linked Block/Graft Copolymers: Effective Synthesis via Functional Macromolecular [2]Rotaxanes

被引：32
作者：
Aoki, Daisuke [1 ]
Uchida, Satoshi [1 ]
Takata, Toshikazu [1 ]
机构：
[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
来源：
ACS MACRO LETTERS | 2014年 / 3卷 / 04期
关键词：
CLICK CHEMISTRY; AMMONIUM GROUP; ROTAXANE; BLOCK; POLYMERS; END; PSEUDOROTAXANE; ACYLATION; DYNAMICS; NETWORK;
D O I：
10.1021/mz5001306
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An effective method to synthesize mechanically linked transformable block polymer was developed utilizing functional macromolecular [2]rotaxane with a "fixed" or "movable" wheel. The interaction between a sec-ammonium and a dibenzo-24-crown-8-ether was the key to control the mobility of the wheel component, indicating the capability of the transformation from linear block copolymer to block/graft copolymer in which the grafting polymer chain is movable along the axle polymer chain.
引用
收藏
页码：324 / 328
页数：5
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