Reactions of Grignard Reagents with Nitrous Oxide

被引：28

作者：

Tskhovrebov, Alexander G. ^{[1
]}

Solari, Euro ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ORGANOMETALLICS | 2014年 / 33卷 / 10期

基金：

瑞士国家科学基金会;

关键词：

OXYGEN-ATOM TRANSFER; N BOND-CLEAVAGE; FRUSTRATED LEWIS PAIRS; 3-COORDINATE MOLYBDENUM(III); DINITROGEN OXIDE; METAL CENTERS; N2O; COMPLEXES; ACTIVATION; OXIDATION;

D O I：

10.1021/om500333y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemical activation of nitrous oxide (N2O) can be achieved by organocalcium, organosodium, and organolithium compounds. Grignard reagents, on the other hand, are believed to be inert. We demonstrate that this generalization is not correct. Some aliphatic Grignard reagents undergo a rapid conversion when subjected to an atmosphere of N2O. Hydrazones are the main reaction products.

引用

页码：2405 / 2408

页数：4

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