Dynamic chirality:: Molecular shuttles and motors

被引：36

作者：

Leigh, David A. ^{[1
]}

Perez, Emilio M. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

SUPRAMOLECULAR CHIRALITY | 2006年 / 265卷

关键词：

dynamics; chirality; catenane; rotaxane; molecular shuttle; molecular machine; molecular motor;

D O I：

10.1007/128_039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To appreciate the technological potential of controlled molecular-level motion one only has to consider that it lies at the heart of virtually every biological process. When we learn how to build synthetic molecular motors and machines that can interface their effects directly with other molecular-level sub-structures and the outside world it will add a new dimension to functional molecule and materials design. In this review we discuss both the influence of chirality on the design of molecular level machines and, in turn, how molecular level machines can control the expression of chirality of a physical response to an inherently achiral stimulus.

引用

页码：185 / 208

页数：24

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