A new one-dimensional oxalato- and acetato-bridged Mn(II) polymer with 1,10-phenanthroline as terminal ligand:: [Mn2(C12N2H8)2(μ-C2O4)(μ-CH3COO)2]n•4nH2O

被引：3
|
作者：
Zhang, Quanzheng [1 ]
Yang, Wenbin [1 ]
Lu, Canzhong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2006年 / 36卷 / 03期
基金：
中国国家自然科学基金;
关键词：
manganese; oxalate; acetate;
D O I：
10.1007/s10870-005-9052-6
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new oxalato- and acetato-bridged Mn(II) polymer, [Mn-2(C12N2H8)(2)(mu-C2O4)(mu-CH3COO)(2)] (n) center dot 4nH(2)O was synthesized and characterized by X-ray diffraction analysis. The compound exhibits a one-dimensional chain-like structure, in which the Mn atom is coordinated by two nitrogen atoms and four carboxyl oxygen atoms with octahedral coordination geometry. As far as we are aware, this type of coordination polymer involving the simultaneously bridging oxalate and acetate ligands has not been studied so far.
引用
收藏
页码：225 / 228
页数：4
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